85250-56-2

Basic information

• Product Name: Benzene, (2-octenylthio)-, (E)-
• CAS NO: 85250-56-2
• Molecular Formula: C14H20S
• Molecular Weight: 220.379
• Mol File: 85250-56-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, (2-octenylthio)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-octenylthio)-, (E)-(85250-56-2)
• EPA Substance Registry System: Benzene, (2-octenylthio)-, (E)-(85250-56-2)

Safety Data

• Hazardous Substances Data: 85250-56-2(Hazardous Substances Data)

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 119450-35-0 (E)-1-acetoxy-4-(phenylthio)-2-butene 
• 14204-24-1 N-(phenylthio)succinimide 
• 3391-86-4 1-octen-3-ol 
• 68883-76-1 (E)-1-chlorooct-2-ene 
• 930-69-8 sodium thiophenolate 
• 4551-15-9 phenylthiotrimethylsilane 
• 84019-04-5 1-(phenylsulfinyl)oct-2-ene 
• 108-98-5 thiophenol 
• 25466-54-0 (Z)-1-bromo-2-octene 
• 79243-01-9 3-(phenylthio)oct-1-ene 
• 111835-83-7 1-pentylprop-2-enyl o-phenylene phosphite 
• 882-33-7 diphenyldisulfane 
• 36602-98-9 2-(oct-2-yn-1-yloxy)tetrahydro-2H-pyran 

Downstream Products

• 104221-11-6 7-[(3R,4R)-2-Hydroxy-2-(2-methyl-propane-2-sulfonylmethyl)-4-((E)-1-phenylsulfanyl-oct-2-enyl)-tetrahydro-furan-3-yl]-hept-5-ynoic acid methyl ester 
• 104221-10-5 7-[(3R,4R)-2-Hydroxy-2-(2-methyl-propane-2-sulfonylmethyl)-4-((E)-1-phenylsulfanyl-oct-2-enyl)-tetrahydro-furan-3-yl]-hept-5-ynoic acid 
• 104220-93-1 7-[(1R,2R,3R)-3-tert-Butoxy-5-oxo-2-((E)-1-phenylsulfanyl-oct-2-enyl)-cyclopentyl]-hept-5-ynoic acid methyl ester 
• 104221-01-4 methyl (E)-9-hydroxy-11-t-butoxy-13-(phenylthio)prost-14-en-5-ynoate 
• 91789-25-2 5-[(2R,3R)-3-((E)-1-Benzenesulfinyl-oct-2-enyl)-2-hydroxy-indan-5-yloxy]-1-pyrrolidin-1-yl-pentan-1-one 
• 91789-33-2 4-[(2R,3R)-3-((E)-1-Benzenesulfinyl-oct-2-enyl)-2-hydroxy-indan-5-yloxy]-1-pyrrolidin-1-yl-butan-1-one 
• 91789-15-0 (1R,2R)-1-((E)-1-Benzenesulfinyl-oct-2-enyl)-6-methoxy-indan-2-ol 
• 91789-09-2 (1S,2S)-1-((E)-1-Benzenesulfinyl-oct-2-enyl)-indan-2-ol 
• 91789-24-1 (1RS),(2RS)-1-hydroxy-1-<(1E)-1-phenylthio-oct-2-enyl>-6-(4-pyrrolidin-1-ylcarbonylbutoxy)indan 
• 91789-32-1 4-[(2R,3R)-2-Hydroxy-3-((E)-1-phenylsulfanyl-oct-2-enyl)-indan-5-yloxy]-1-pyrrolidin-1-yl-butan-1-one 
• 104220-92-0 (3R,4R)-3-tert-Butoxy-4-((E)-1-phenylsulfanyl-oct-2-enyl)-cyclopentanone 

Relevant articles and documents

Direct synthesis of allyl sulfides from allyl alcohols and thiols

In the presence of boron trifluoride-diethyl ether complex, various allyl alcohols [(-)-myrtenol, geraniol, cinnamyl alcohol, linalool, 1-octen-3-ol, 2-hydroxybenzyl alcohol and bicyclic diols] were reacted with thiophenol, 1-butanethiol, trimethyl(phenylthio)silane or hexamethylsilane in dichloromethane at room temperature to give the corresponding allyl sulfides in good to excellent yields. The mild conditions for this transformation allowed chemoselectivity.

The Preparation of Some Octenyl Sulfides from Oct-1-en-3-ol and Oct-2-en-1-ol

(E)- and (Z)-1-(Phenylthio)oct-2-ene, (E)-1-(methylthio)- and 1-(t-butylthio)-oct-2-ene, S- N,N-dimethylthiocarbamate, S- N,N-dimethylthiocarbamate, (E)-(oct-2-enylthio)benzothiazole, and S- N,N,N',N'-tetramethylphosphorodiamidothioate have been prepared by nucleophilic substitution reactions and - and -sigmatropic shifts involving intermediates prepared from oct-1-en-3-ol and (E)- and (Z)-oct-2-en-1-ol.

A Dual Regiocontrol in the Copper-catalysed Grignard Reaction with Primary Allylic Acetates

The reaction of primary allylic acetates with Grignard reagents in the presence of catalytic amounts of Li2CuCl4 can be regiochemically controlled to give either α- or γ-substitution of the allylic acetoxy group.