93712-84-6

Basic information

• Product Name: ReH5(PMe2Ph)3
• CAS NO: 93712-84-6
• Molecular Weight: 605.694
• Mol File: 93712-84-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ReH5(PMe2Ph)3(CAS DataBase Reference)
• NIST Chemistry Reference: ReH5(PMe2Ph)3(93712-84-6)
• EPA Substance Registry System: ReH5(PMe2Ph)3(93712-84-6)

Safety Data

• Hazardous Substances Data: 93712-84-6(Hazardous Substances Data)

Upstream product

• 135707-76-5 mer-hydridobis(ethylene)tris(dimethylphenylphosphine)rhenium(I) 
• 135707-77-6 cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I) 

Downstream Products

• 122968-01-8 K⁽¹⁺⁾*{ReH₄(P(CH₃)2C₆H₅)3}^(1-)=K{ReH₄(P(CH₃)2C₆H₅)3} 
• 144564-84-1 (C₅H₅)2Y(C₄H₈O)H₄Re(P(CH₃)2(C₆H₅))3 
• 144564-88-5 (C₅H₅)2Lu(C₄H₈O)H₄Re(P(CH₃)2(C₆H₅))3 
• 86323-24-2 (ReH₅(P(CH₃)2C₆H₅)3)2Cu⁽¹⁺⁾*PF₆^(1-)=((ReH₅(P(CH₃)2C₆H₅)3)2Cu)PF₆ 
• 80524-90-9 ReH3(PMe2Ph)3(η2-cyclopentene) 
• 80524-91-0 ReH₂[P(CH₃)2C₆H₅]2(C₅H₅) 
• 58513-89-6 H₅Re[P(CH₃)2C₆H₅]2 
• 173787-83-2 ReH(SC₅H₄N)2F(PC₂H₆C₆H₅)2⁽¹⁺⁾*BF₄^(1-)=[ReH(SC₅H₄N)2F(PC₂H₆C₆H₅)2]BF₄ 
• 173787-81-0 ReH(SC₅H₄N)(PC₂H₆C₆H₅)4⁽¹⁺⁾*BF₄^(1-)=[ReH(SC₅H₄N)(PC₂H₆C₆H₅)4]BF₄ 
• 14710-16-8 fac-ReCl₃(PMe₂Ph)3 
• 1231205-01-8 [Re(η2-CH2CC(OH)Ph2)Cl2(PMe2Ph)3] 
• 1231204-97-9 [Re(η2-CH2CSiMe3)Cl2(PMe2Ph)3] 
• 1231204-95-7 [Re(η2-CH2C(CH2)4CH3)Cl2(PMe2Ph)3] 
• 14710-16-8 mer-trichlorotris(dimethylphenylphosphine)rhenium(III) 

Relevant articles and documents

Synthesis and structure of hydrido bis(ethylene) and hydrido dinitrogen complexes of rhenium(I) having dimethylphenylphosphine ligands

mer-Hydridobis(ethylene)tris(dimethylphenylphosphine)rhenium(I) (1) and cis-hydrido(dinitrogen)-tetrakis(dimethylphenylphosphine)rhenium(I) (2) have been prepared by the reaction of mer-trichloro-tris(dimethylphenylphosphine)rhenium(I) with ethyllithium and n-propyllithium, respectively. X-ray structure analysis reveals that which complexes are octahedral, and in the former complex the two coordinated ethylenes occupy sites perpendicular to each other in cis positions and in the latter complex hydrido and dinitrogen ligands in cis positions. The coordinated ethylene and dinitrogen can be smoothly displaed by dihydrogen to give known trihydrido- or pentahydridorhenium complexes. Crystal data for 1: space group P1, Z = 2, a = 9.285 (3) ?, b = 19.229 (5) ?, c = 9.044 (3) ?, α = 93.47 (3)°, β = 120.16 (2)°, γ = 90.23 (3)°, V = 1392.5 (8) ?3, R = 0.0653, Rw = 0.0641, based on 3959 reflections with F > 3σ(F). Crystal data for 2: space group P21/a, Z = 4, a = 27.49 (1) ?, b = 10.113 (2) ?, c = 12.235 (6) ?, β = 91.94 (4)°, V = 3424 (2) ?3, R = 0.0464, Rw = 0.0533, based on 4129 reflections with F > 3σ(F).