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Cadmium acetate

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Cadmium acetate

EINECS 208-853-2
CAS No. 543-90-8 Density 1.068g/cm3
PSA 37.30000 LogP 0.08840
Solubility soluble H2O, alcohol [HAW93] Melting Point 255°C
Formula C2H4 O2 . 1/2 Cd Boiling Point 117.1 °C at 760 mmHg
Molecular Weight 230.499 Flash Point 40 °C
Transport Information N/A Appearance N/A
Safety Confirmed human carcinogen. Poison by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS. Risk Codes 20/21/22-50/53
Molecular Structure Molecular Structure of 543-90-8 (Cadmium acetate) Hazard Symbols F,N,T+
Synonyms

Aceticacid, cadmium salt (8CI,9CI); Cadmium acetate (6CI,7CI); Bis(acetoxy)cadmium;C.I. 77185; Cadmium diacetate; Cadmium ethanoate; Cadmium(II) acetate

Article Data 29

Cadmium acetate Chemical Properties

Chemistry informtion about Cadmium(II) Acetate (CAS NO.543-90-8) is:
IUPAC Name: Cadmium(2+) Diacetate
Synonyms: Ai3-01414 ; Bis(Acetoxy)Cadmium ; C.I.77185 ; Cadmium(II)Acetate ; Cadmiumdiacetate ; Cadmiumethanoate ; Ci77185 ; Cadmium Acetate
MF: C4H6CdO4
MW: 230.5
EINECS: 208-853-2
Melting Point: 255°C 
Flash Point: 40 °C
Boiling Point: 117.1 °C at 760 mmHg
Vapour Pressure: 13.9 mmHg at 25°C
Enthalpy of Vaporization: 23.7 kJ/mol
Following is the molecular structure of Cadmium(II) Acetate (CAS NO.543-90-8) is:

Cadmium acetate Uses

 Cadmium(II) Acetate (CAS NO.543-90-8) is used for glazing ceramics and pottery; in electroplating baths, in dyeing and printing textiles; and as an analytic reagent for sulfur, selenium and tellurium.

Cadmium acetate Production

It is prepared by treating cadmium oxide with acetic acid. The compound may also be prepared by treating cadmium nitrate with acetic anhydride.Its raw materials: Acetic acid glacial --> Nitric acid --> Hydrogen peroxid e--> Cadmium .

Cadmium acetate Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 14mg/kg (14mg/kg)   Toxicology and Applied Pharmacology. Vol. 49, Pg. 41, 1979.
rat LD50 intraperitoneal 74900ug/kg (74.9mg/kg)   "Evaluation of the Impact of Cadmium on the Health of Man", Oxford, UK. Pergamon Press Ltd., 1978Vol. -, Pg. 67, 1978.
rat LD50 oral 333mg/kg (333mg/kg)   "Evaluation of the Impact of Cadmium on the Health of Man", Oxford, UK. Pergamon Press Ltd., 1978Vol. -, Pg. 67, 1978.

Cadmium acetate Consensus Reports

IARC Cancer Review: Group 1 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Cadmium and its compounds are on the Community Right-To-Know List.

Cadmium acetate Safety Profile

Confirmed human carcinogen. Poison by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS.
Hazard Codes:
FlammableF
Risk Statements:
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:
S22:Do not breathe dust.
RIDADR: 2570
HazardClass: 6.1(b)
PackingGroup: III

Cadmium acetate Standards and Recommendations

OSHA PEL: TWA 5 µg(Cd)/m3
ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 µg/g creatinine in urine; 5 µg/L in blood
NIOSH REL: (Cadmium) Reduce to lowest feasible level

Cadmium acetate Specification

Cadmium(II) Acetate (CAS NO.543-90-8) is a odorless colorless solid. It can sinks and mixes with water. It slowly oxidized by moist air to form cadmium oxide [Merck 11th ed. 1989].Also it is soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Special Hazards of Combustion Products: Toxic cadmium oxide fumes may form in fires [USCG, 1999]. Inhalation causes coughing, sneezing, Toxic cadmium oxide fumes may form in fires.

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