Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Chromocene

Related Products

Hot Products

Name

Chromocene

EINECS 215-036-4
CAS No. 1271-24-5 Density g/cm3
PSA 0.00000 LogP 2.04300
Solubility insoluble in water Melting Point 172°C to 173°C
Formula C10H10 Cr Boiling Point 41.5 °C at 760 mmHg
Molecular Weight 182.185 Flash Point °C
Transport Information UN# 2846 Appearance bordeaux crystalline powder
Safety 26-37/39 Risk Codes R36/37/38   
Molecular Structure Molecular Structure of 1271-24-5 (Chromocene) Hazard Symbols
Synonyms

Chromium,di-p-cyclopentadienyl- (8CI);Chromium, dicyclopentadienyl- (6CI,7CI); Bis(cyclopentadiene)chromium;Bis(cyclopentadiene)chromium(II); Bis(cyclopentadienyl)chromium;Bis(cyclopentadienyl)chromium(II); Bis(h5-cyclopentadienyl)chromium; Chromium, bis(h5-2,4-cyclopentadien-1-yl)-; Di(h5-cyclopentadienyl)chromium;Dicyclopentadienylchromium

Article Data 12

Chromocene Chemical Properties

Molecular Structure of Chromocene (CAS NO.1271-24-5):

IUPAC Name: Chromium(2+); cyclopenta-1,3-diene 
Molecular Formula: C10H10Cr
Molecular Weight: 182.18
EINECS: 215-036-4 
Density: 1.43 g/cm3, solid
Melting point: 168-170 °C
Melting Point: 168-170 °C(lit.)
Enthalpy of Vaporization: 27.4 kJ/mol
Boiling Point: 41.5 °C at 760 mmHg
Vapour Pressure: 418 mmHg at 25 °C
Sensitive: Air & Moisture Sensitive
Classification Code: Mutation data 
Product Categories: Organometallics 
Solubility in water: decomposes in water
Appearance: Red needles or reddish-purple solid.
Canonical SMILES: [CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cr+2]
InChI: InChI=1S/2C5H5.Cr/c2*1-2-4-5-3-1;/h2*1-5H;/q2*-1;+2
InChIKey: TYYBBNOTQFVVKN-UHFFFAOYSA-N

Chromocene Production

 Chromocene (CAS NO.1271-24-5) is prepared by the following route:
 CrCl2 + 2 NaC5H5 → Cr(C5H5)2 + 2 NaCl

Chromocene Safety Profile

Safety Information of Chromocene (CAS NO.1271-24-5):
Hazard Codes:HarmfulXn,IrritantXi
Risk Statements: 20/21/22-36/37/38 
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S37/39:Wear suitable gloves and eye/face protection.
RIDADR: 1325
WGK Germany: 3
RTECS: GB7600000
HazardClass: 4.2
PackingGroup: I

Chromocene Specification

 Chromocene (CAS NO.1271-24-5), its Synonyms are Bis(cyclopentadiene)chromium ; Bis(cyclopentadiene)chromium(II) ; Bis(cyclopentadienyl)chromium ; Bis(cyclopentadienyl)chromium(II) ; CCRIS 5974 ; Chromium, dicyclopentadienyl- ; Di((eta-5)-cyclopentadienyl)chromium ; Dicyclopentadienylchromium ; Bis(eta5-cyclopenta-2,4-dien-1-yl)chromium . It is very sensitive to exposure to air and moisture (decomposition is not vigorous). 
 Chromocene reacts with water and alcohols. . It's reaction with alcohols produces pyrophoric metal alkoxides (dialkoxychromium and cyclopentadiene).It is often abbreviated Cp2Cr. This sandwich compound is structurally similar to ferrocene but does not follow the 18-electron rule because it only has 16 electrons and therefore it also paramagnetic and far more reactive.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 1271-24-5