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Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II)

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Name

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II)

EINECS N/A
CAS No. 132071-87-5 Density N/A
PSA 27.18000 LogP 10.55540
Solubility N/A Melting Point >300oC
Formula C44H32 Cl2 P2 Ru Boiling Point 724.3oC at 760 mmHg
Molecular Weight 794.662 Flash Point 419oC
Transport Information N/A Appearance N/A
Safety Risk Codes R36/37/38   
Molecular Structure Molecular Structure of 132071-87-5 (DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)) Hazard Symbols
Synonyms

Ruthenium,[[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-kP]]dichloro-, [SP-4-2-(R)]-;Phosphine, [1,1'-binaphthalene]-2,2'-diylbis[diphenyl-, ruthenium complex,(R)-; Ruthenium,[[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine]-P,P']dichloro-,[SP-4-2-(R)]-; [2,2'-Bis(diphenylphosphino)-(R)-1,1'-binaphthyl]dichlororuthenium

Article Data 4

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II) Chemical Properties

Molecular structure of Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II) (CAS NO.132071-87-5) is:

Product Name: Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II)
CAS Registry Number: 132071-87-5
Molecular Formula: C44H32Cl2P2Ru
Molecular Weight: 794.65
Melting point: >300 °C
Flash Point: 419 °C 
Enthalpy of Vaporization: 102.01 kJ/mol 
Boiling Point: 724.3 °C at 760 mmHg 
Vapour Pressure: 5.55E-20 mmHg at 25°C 
Product Categories: Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds
SMILES: [Ru+2].[Cl-].[Cl-].c8c1ccccc1c(c5c2ccccc2ccc5P(c3ccccc3)c4ccccc4)c(P(c6ccccc6)c7ccccc7)c8
InChI: InChI=1/C44H32P2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2
InChIKey: YEKBVMDAGDTOQB-NUQVWONBAL

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II) Safety Profile

Safty information about Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II) (CAS NO.132071-87-5) is:
Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39-36/37 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S36/37:Wear suitable protective clothing and gloves.

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II) Specification

 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II) , its cas register number is 132071-87-5. It also can be called Ruthenium,[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-kP]]dichloro-, (SP-4-2)- (9CI) ; Ruthenium(2+) dichloride 1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane) (1:1) .

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