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Basic Information
| CAS No.: | 115-32-2 |
|---|---|
| Name: | Dicofol |
| Molecular Structure: | |
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|
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| Formula: | C14H9Cl5O |
| Molecular Weight: | 370.49 |
| Synonyms: | Benzhydrol,4,4'-dichloro-a-(trichloromethyl)-(8CI);1,1-Bis(4-chlorophenyl)-2,2,2-trichloroethanol;1,1-Bis(p-chlorophenyl)-2,2,2-trichloroethanol;2,2,2-Trichloro-1,1-bis(p-chlorophenyl)ethanol;2,2,2-Trichloro-1,1-di(4-chlorophenyl)ethanol;4,4'-Dichloro-a-(trichloromethyl)benzhydrol;AFD25;Acarin;Agravertin;CPCA;Decofol;Dichlorokelthane;Dicofol;ENT 23,648;Ethanol, 2,2,2-trichloro-1,1-bis(4-chlorophenyl)-;FW 293;Kelthane;Kelthane A;Milbol;Mitigan;p,p'-Kelthane; |
| EINECS: | 204-082-0 |
| Density: | 1.532 g/cm3 |
| Melting Point: | 78.5 °C |
| Boiling Point: | 454.7 °C at 760 mmHg |
| Flash Point: | 228.8 °C |
| Solubility: | <0.01 g/100 mL at 22 °C in water |
| Appearance: | white or grey powder, or colourless crystals |
| Hazard Symbols: |
 Xn,  N,  T,  F
|
| Risk Codes: | 21/22-38-43-50/53-39/23/24/25-23/24/25-11 |
| Safety: | 36/37-60-61-45-16-7 |
| Transport Information: | UN 2761/3077 |
| PSA: | 20.23000 |
| LogP: | 5.59950 |
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Dicofol
Chemistry
The molecular formula of 1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL(115-32-2) is C14H9Cl5O and its formula weight is 370.48g/mol.Its EINECS is 204-082-0 and liansport information is UN 2761/3.The appearance of 1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL (115-32-2) is white or grey powder, or colourless crystals.The density of 1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL (115-32-2) is 1.45 g/cm3 and it has a melting point of 78.5°C.The boiling point is 454.7 °C at 760 mmHg.The refractive index is about 1.626 and molar refractivity is 85.61 cm3.Molar volume is 241.8 cm3 and polarizability is 33.93 10-24cm3.Surface tension is 51.8 dyne/cm and enthalpy of vaporization is 75.28 kJ/mol.Its flash point is 228.8 °C and the vapor pressure is 4.64E-09 mmHg at 25°C.1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL (115-32-2) has the property of being dissolved in acetone, ethyl acetate, xylene and other organic solvents,slightly dissolved in water.The solubility of 1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL (115-32-2) is less than 0.01 g/100 mL in water at 22°C.It is stable and combustible.It is incompatible with strong oxidizing agents and hydrolyzes in basic solution.It corrodes some metals.
The chemical synonyms of 1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL (115-32-2) are 1,1,1-Trichlor-2,2-bis(4-chlorphenyl)-aethanol;1,1-Bis(4-chlorophenyl)-2,2,2-trichloroethanol;2,2,2-Trichloor-1,1-bis(4-chloor fenyl)-ethanol;2,2,2-trichloor-1,1-bis(4-chloorfenyl)-ethanol;2,2,2-Trichlor-1,1-bis(4-chlor-phenyl)-aethanol;2,2,2-trichloro-1,1-bis(4-chlorophenyl)-ethanol(french);2,2,2-Trichloro-1,1-bis(4-cloro-fenil)-etanolo and 2,2,2-trichloro-1,1-bis(p-chlorophenyl)-ethano.Its product categories is INSECTICIDE;2000/60/EC;Alphabetic;Analytical Standards;European Community: ISO and DIN;KMethod Specific;AcaricidesPesticides&Metabolites;Alpha sort;D;DAlphabetic;DIA - DICMethod Specific;Endocrine Disruptors (Draft);EPA;Pesticides and Metabolites. The molecular structure of 1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL (115-32-2) is
.
The chemical synonyms of 1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL (115-32-2) are 1,1,1-Trichlor-2,2-bis(4-chlorphenyl)-aethanol;1,1-Bis(4-chlorophenyl)-2,2,2-trichloroethanol;2,2,2-Trichloor-1,1-bis(4-chloor fenyl)-ethanol;2,2,2-trichloor-1,1-bis(4-chloorfenyl)-ethanol;2,2,2-Trichlor-1,1-bis(4-chlor-phenyl)-aethanol;2,2,2-trichloro-1,1-bis(4-chlorophenyl)-ethanol(french);2,2,2-Trichloro-1,1-bis(4-cloro-fenil)-etanolo and 2,2,2-trichloro-1,1-bis(p-chlorophenyl)-ethano.Its product categories is INSECTICIDE;2000/60/EC;Alphabetic;Analytical Standards;European Community: ISO and DIN;KMethod Specific;AcaricidesPesticides&Metabolites;Alpha sort;D;DAlphabetic;DIA - DICMethod Specific;Endocrine Disruptors (Draft);EPA;Pesticides and Metabolites. The molecular structure of 1,1-BIS(p-CHLOROPHENYL)-2,2,2-TRICHLORO-ETHANOL (115-32-2) is
.Uses
It is used in cancer bioassay and as miticid.
Toxicity Data With Reference
| 1. | sce-hmn:lym 1 µmol/L | ARTODN Archives of Toxicology. 52 (1983),221. | ||
| 2. | orl-rat LD50:575 mg/kg | WRPCA2 World Review of Pest Control. 9 (1970),119. | ||
| 3. | skn-rat LD50:100 mg/kg | WRPCA2 World Review of Pest Control. 9 (1970),119. | ||
| 4. | ipr-rat LD50:1150 mg/kg | TXAPA9 Toxicology and Applied Pharmacology. 15 (1969),30. | ||
| 5. | orl-mus LD50:420 mg/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 19 (9)(1975),55. | ||
| 6. | orl-rbt LD50:1810 mg/kg | TXAPA9 Toxicology and Applied Pharmacology. 1 (1959),119. | ||
| 7. | skn-rbt LD50:1870 mg/kg | GUCHAZ Guide to the Chemicals Used in Crop Protection 6 (1973),195. | ||
| 8. | orl-gpg LD50:1810 mg/kg | 85DPAN Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow, Berlin, Germany.: Verlag Paul Parey,1971/76 | ||
| 9. | orl-ckn LD50:4365 mg/kg | VETNAL Veterinariya. 60 (10)(1984),64. |
Consensus Reports
IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 30 (1983),p. 87.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-90 ,1978. ; No Evidence: rat NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-90 ,1978. . Community Right-To-Know List.
Safety Profile
Poison by ingestion and skin contact. Moderately toxic by intraperitoneal route. Human mutation data reported. Questionable carcinogen with experimental carcinogenic data. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of Cl−.
Hazard symbols is
Xn;
N;
T;
F.
Risk statements is 21/22-38-43-50/53-39/23/24/25-23/24/25-11.
20/21: Harmful by inhalation and in contact with skin.
23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
38: Irritating to the skin.
43: May cause sensitization by skin contact.
11: Highly Flammable.
Safety statements is 36/37-60-61-45-16-7.
36/37: Wear suitable protective clothing and gloves.
60: This material and/or its container must be disposed of as hazardous waste.
61: Avoid release to the environment. Refer to special instructions safety data sheet.
16: Keep away from sources of ignition - No smoking.
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
7: Keep container tightly closed.
Hazard symbols is
Xn;N;T;F.Risk statements is 21/22-38-43-50/53-39/23/24/25-23/24/25-11.
20/21: Harmful by inhalation and in contact with skin.
23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
38: Irritating to the skin.
43: May cause sensitization by skin contact.
11: Highly Flammable.
Safety statements is 36/37-60-61-45-16-7.
36/37: Wear suitable protective clothing and gloves.
60: This material and/or its container must be disposed of as hazardous waste.
61: Avoid release to the environment. Refer to special instructions safety data sheet.
16: Keep away from sources of ignition - No smoking.
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
7: Keep container tightly closed.
Specification
Its extinguishing agent is sand, dry powder and foam.