Any of a number of organic compounds that increase the octane number of a gasoline when added in low percentages by reducing knock, especially in high-compression engines. Knock is caused by spontaneous oxidation reactions in the cylinder head, resulting in loss of power and characteristic ignition noise. Branched-chain hydrocarbon gasolines ameliorate this problem, and antiknock additives virtually eliminate it. Tetraethyllead, the most effective of these, has been used for many years, but its contribution to air pollution has almost eliminated its use in automotive fuels. Lead-free gasolines are now used in conjunction with catalytic converters. The antiknock agents used in them are nonmetallic compounds such as methyl-tert-butyl ether (MTBE) or a mixture of methanol and tert-butyl alcohol.See Octane Number; Gasoline.
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