An electrolytic process for removing impurities from lead in which pure lead is deposited on a thin cathode of pure lead from an anode containing as much as 10% of silver, gold, bismuth, copper, antimony, arsenic, selenium, and other impurities. The electrolyte is lead fluosilicate and fluosilicic acid. The scrap anodes and the residues of impurities associated with them are either recast into anodes or treated to recover antimony lead, silver, gold, bismuth, etc.