- 21947-98-8N-Boc-S-Trityl-L-cysteine
- 21948-10-7Serine,O-(phenylmethyl)-, phenylmethyl ester, hydrochloride (9CI)
- 219485-21-92-Quinoxalinecarboxylicacid, 3,4-dihydro-3-oxo-7-(trifluoromethyl)-
- 21948-70-9Pyrazine,2-(methylthio)-
- 219492-12-3Benzenamine,4-methyl-3-(phenylmethoxy)-
- 219503-81-81H-Indazole-1-carboxylicacid, 6-amino-, 1,1-dimethylethyl ester
- 219508-19-71H-Indole-6-carboxylic acid, 3-bromo-
- 219508-62-01H-Indole-1-carboxylicacid, 6-amino-, 1,1-dimethylethyl ester
- 219509-79-21,4-Piperazinedicarboxylicacid, 1-(1,1-dimethylethyl) 4-methyl ester
- 219511-71-4Carbamic acid,N-(aminoiminomethyl)-, 1,1-dimethylethyl ester
Hot Products
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
- 7631-86-9Silicon dioxide
- 302-79-4Tretinoin
- 77-92-9Citric acid
|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
| Name |
Diisopinocampheylborane |
EINECS | N/A |
| CAS No. | 21947-87-5 | Density | N/A |
| PSA | 0.00000 | LogP | 5.40410 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C20H35B | Boiling Point | 351.475oC at 760 mmHg |
| Molecular Weight | 286.309 | Flash Point | 166.367oC |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Borane,bis(2,6,6-trimethylbicyclo[3.1.1]hept-3-yl)-, [1S-[1a,2b,3a(1R*,2S*,3R*,5R*),5a]]-;Borane, di-3-pinanyl-, (+)-(8CI);(+)-Diisopinocampheylborane;d-Diisopinocampheylborane; |
Article Data | 18 |
Diisopinocampheylborane Synthetic route
- 7785-26-4
(-)-α-pinene
- 21947-87-5
L-diisopinocampheylborane
| Conditions | Yield |
|---|---|
| With borane N-ethyl-N-isopropylaniline complex In 1,4-dioxane hydroboration; | 99% |
| With dimethylsulfide borane complex In tetrahydrofuran at 20℃; Inert atmosphere; | 73% |
| With sodium tetrahydroborate; boron trifluoride diethyl etherate |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 20℃; for 16h; Inert atmosphere; | 82% |
| In tetrahydrofuran at 0℃; for 0.5h; | 60% |
| In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; | 52% |
| In tetrahydrofuran | |
| In tetrahydrofuran at 0℃; |
- 13292-87-0
dimethylsulfide borane complex
- 127-91-3
(1R,5R)-(+)-β-pinene
- 21947-87-5
L-diisopinocampheylborane
| Conditions | Yield |
|---|---|
| In tetrahydrofuran pinene was slowly added to THF soln. of BMS at 0°C (N2); stirring for 2.5 h; evapn.; |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere; stereoselective reaction; |
- 15095-61-1
1-benzyl-3-methyl-1H-imidazol-3-ium iodide
- 21947-87-5
L-diisopinocampheylborane
| Conditions | Yield |
|---|---|
| With potassium hexamethylsilazane In tetrahydrofuran at 25℃; Inert atmosphere; Schlenk technique; | 83% |
- 100-52-7
benzaldehyde
- 21947-87-5
L-diisopinocampheylborane
- 155818-57-8
3-phenyl-1-(tributylstannyl)-1,2-propadiene
| Conditions | Yield |
|---|---|
| In diethyl ether Sn compd. in Et2O treated with B compd. at 0°C for 5 h, C6H5CHO added at -78°C, stirred at -78°C for 8 h; NaHCO3 and H2O2 added at 0°C; 94 % ee; | 76% |
- 104-53-0
3-phenyl-propionaldehyde
- 21947-87-5
L-diisopinocampheylborane
- 155818-57-8
3-phenyl-1-(tributylstannyl)-1,2-propadiene
| Conditions | Yield |
|---|---|
| In diethyl ether Sn compd. in Et2O treated with B compd. at 0°C for 5 h, C6H5(CH2)2CHO added at -78°C, stirred at -78°C for 8 h; NaHCO3 and H2O2 added at 0°C; 94 % ee; | 71% |
- 21947-87-5
L-diisopinocampheylborane
| Conditions | Yield |
|---|---|
| With potassium hexamethylsilazane In tetrahydrofuran at 25℃; Inert atmosphere; Schlenk technique; | 60% |
- 65039-06-7
N-methyl-N'-phenyl imidazolium iodide
- 21947-87-5
L-diisopinocampheylborane
| Conditions | Yield |
|---|---|
| With potassium hexamethylsilazane In tetrahydrofuran at 25℃; Inert atmosphere; Schlenk technique; | 56% |
- 4333-62-4
1,3-dimethylimidazolim iodide
- 21947-87-5
L-diisopinocampheylborane
| Conditions | Yield |
|---|---|
| With potassium hexamethylsilazane In tetrahydrofuran at 20℃; for 20h; Sealed tube; Inert atmosphere; Glovebox; | 37% |
| With potassium hexamethylsilazane In tetrahydrofuran at 25℃; for 20h; Inert atmosphere; Schlenk technique; | 37% |
Diisopinocampheylborane Chemical Properties
Molecular Structure of Diisopinocampheylborane (CAS No.21947-87-5):
Molecular Formula: C20H35B
Molecular Weight: 286.30
CAS No: 21947-87-5
IUPAC Name: bis {(1S,2S,3S,5R)-2,6,6-Trimethylbicyclo [3.1.1] heptan-3-yl} borane
Diisopinocampheylborane History
Diisopinocampheylborane was reported in 1961 by Zweifel and Brown in a pioneering demonstration of asymmetric synthesis using boranes.
Diisopinocampheylborane Uses
Diisopinocampheylborane (CAS No.21947-87-5) is mainly used for the synthesis of chiral secondary alcohols.
Diisopinocampheylborane Production
Diisopinocampheylborane is now more commonly generated from borane-methyl sulfide (BMS).
Diisopinocampheylborane Specification
Diisopinocampheylborane (CAS No.21947-87-5), its synonyms are (+)-Diisopinocampheylborane ; Bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]borane .
What can I do for you?
Get Best Price
