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4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
Conditions | Yield |
---|---|
With tributylphosphine; iodine In tetrahydrofuran; acetonitrile at 20℃; for 0.166667h; Inert atmosphere; | 95% |
acetone
bis[2-(diphenylphosphino)phenyl] ether
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid In toluene at 200℃; for 16h; Temperature; Inert atmosphere; | 95% |
1,1'-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis-1,1-diphenylphosphine oxide
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
Conditions | Yield |
---|---|
With bis(2-chlorophenyl)borinic acid; phenylsilane In toluene at 80℃; for 18h; Inert atmosphere; | 89% |
With 1,3-diphenyl-disiloxane In toluene at 110℃; Sealed tube; chemoselective reaction; | 79% |
9,9-dimethylxanthene
chloro-diphenylphosphine
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
Conditions | Yield |
---|---|
Stage #1: 9,9-dimethylxanthene With N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium In tert-butyl methyl ether; cyclohexane at 6 - 10℃; Stage #2: In cyclohexane; water at 20℃; for 14h; Stage #3: chloro-diphenylphosphine In cyclohexane; water at 10 - 20℃; for 5.16667h; | 88% |
Stage #1: 9,9-dimethylxanthene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane at -78 - 25℃; for 17h; Stage #2: chloro-diphenylphosphine In hexane at 25℃; for 16h; Cooling with ice; | 84% |
Stage #1: 9,9-dimethylxanthene With N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium In tert-butyl methyl ether; cyclohexane at 10 - 20℃; for 16h; Stage #2: chloro-diphenylphosphine In cyclohexane; water at 20℃; for 5.75h; | 77% |
9,9-dimethylxanthene
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
Conditions | Yield |
---|---|
Stage #1: 9,9-dimethylxanthene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane at -78 - 25℃; for 17h; Stage #2: diphenylphosphonium chloride In hexane at 25℃; for 16h; Cooling with ice; | 84% |
9,9-dimethylxanthene
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
Conditions | Yield |
---|---|
Stage #1: 9,9-dimethylxanthene With bis 1,2-(dimethylamino)ethylene; sec.-butyllithium In tert-butyl methyl ether at 10 - 20℃; for 16h; Stage #2: With chloro-diphenylphosphine at 20℃; for 6.25h; |
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
1,1'-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis-1,1-diphenylphosphine oxide
Conditions | Yield |
---|---|
With dihydrogen peroxide In dichloromethane at 0℃; for 2h; | 100% |
With dihydrogen peroxide In dichloromethane; water at 0℃; for 4h; | 99% |
With dihydrogen peroxide In 1,4-dioxane; water for 2h; | 95% |
dichlorotetrakis(triphenylphosphine)ruthenium(II)
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
RuCl2(PPh3)(Xantphos)
Conditions | Yield |
---|---|
In (2)H8-toluene for 3h; Inert atmosphere; Schlenk technique; Reflux; | 100% |
In (2)H8-toluene for 5h; Inert atmosphere; Schlenk technique; Reflux; | 100% |
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
Conditions | Yield |
---|---|
In toluene at 60℃; for 4h; | 100% |
Conditions | Yield |
---|---|
In tetrahydrofuran | 100% |
Molecule structure of Dimethylbisdiphenylphosphinoxanthene (CAS NO.161265-03-8):
Molecular Weight: 578.6183 g/mol
Molecular Formula: C39H32OP2
Melting Point: 224-228 °C(lit.)
Boiling Point: 665.7 °C at 760 mmHg
Flash Point: 449.9 °C
Enthalpy of Vaporization: 94.35 kJ/mol
Vapour Pressure: 7.61E-17 mmHg at 25 °C
InChI: InChI=1/C39H32OP2/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChIKey: CXNIUSPIQKWYAI-UHFFFAOYAQ
Product Categories: Phosphines; Amino Acid Derivatives; Phosphine Ligands; Synthetic Organic Chemistry
Dimethylbisdiphenylphosphinoxanthene (CAS NO.161265-03-8) is used as a ligand for Buchwald, Suzuki and other coupling reactions
Hazard Codes: Xn
Risk Statements: 37-20/22
R37:Irritating to respiratory system
R20/22:Harmful by inhalation and if swallowed.
Safety Statements: 37/39-26
S37/39:Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3
Dimethylbisdiphenylphosphinoxanthene (CAS NO.161265-03-8) is also named as (9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine) ; [5-(Diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl](diphenyl)phosphine ; phosphine, 1,1'-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl- ; Xanthene, 4,5-bis(diphenylphosphino)-9,9-dimethyl- ; 4,5-Bis(diphenylphosphino)-9,9-Dimethylxanthene . Dimethylbisdiphenylphosphinoxanthene (CAS NO.161265-03-8) is white to light yellow crystals.