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Cas Database |
| Name |
Disperse Blue 7 |
EINECS | N/A |
| CAS No. | 3179-90-6 | Density | 1.607g/cm3 |
| PSA | 139.12000 | LogP | 0.82760 |
| Solubility | N/A | Melting Point |
215-220ºC |
| Formula | C18H18 N2 O6 | Boiling Point | 757.4°Cat760mmHg |
| Molecular Weight | 358.351 | Flash Point | 411.8°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Moderately toxic by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Anthraquinone,1,4-dihydroxy-5,8-bis[(2-hydroxyethyl)amino]- (7CI,8CI); Celliton Fast Blue GreenB (6CI); 1,4-Bis(b-hydroxyethylamino)-5,8-dihydroxyanthraquinone;1,4-Bis[(2-hydroxyethyl)amino]-5,8-dihydroxyanthraquinone;1,4-Bishydroxyethylamino-5,8-dihydroxy-9,10-anthraquinone;1,4-Diethanolamino-5,8-dihydroxyanthraquinone; 1,4-Dihydroxy-5,8-bis[(2-hydroxyethyl)amino]anthraquinone;5,8-Dihydroxy-1,4-bis[(2-hydroxyethyl)amino]anthraquinone; Acetate TurquoiseBlue B; Acetoquinone Light Green Blue JL; Amacel Green Blue B; Amacel GreenBlue G; Artisil Blue Green GP; C.I. 62500; C.I. Disperse Blue 7; C.I. SolventBlue 69; Celanthrene Fast Blue 2G; Celliton Blue Green B; Celliton Fast BlueGreen BA-CF; Celutate Green Blue BGH; Cibacet Blue Green C; Cibacet Blue GreenCB; Cibacet Turquoise Blue 2G; Cibacet Turquoise Blue 4G; Cibacet TurquoiseBlue G; Cilla Fast Blue Green B; Diacelliton Fast Blue Green B; Disperse Blue7; Disperse Blue Green; Dispersive blue-green; Dispersol Blue 7G; Duranol BlueGreen B; Duranol Printing Blue Green B; Esteroquinone Light Blue 4JL; FenacetFast Turquoise B; Interchem Acetate Green Blue ALF; Interchem Hisperse GreenBlue ALFH; Miketon Fast Turquoise Blue G; NSC 227207; Nacelan Blue CBG;Nyloquinone Blue 4J; Palanil Blue 7G; Perliton Blue Green B; Samaron Blue 5G;Seriplas Glue Green BW; Serisol Fast Blue Green B; Serisol Fast Blue Green BW;Setacyl Blue 6GN; Setacyl Blue Green P-BS; Setacyl Turquoise Blue 2G; SetacylTurquoise Blue 4G; Setacyl Turquoise Blue G; Setacyl Turquoise Blue GD;Supracet Blue Green B; Supracet Fast Green Blue B; Terasil Blue Green CB;Terasil Turquoise Blue G |
Article Data | 7 |
Disperse Blue 7 Synthetic route
- 112996-70-0
5,8-Dihydroxy-1,4-bis-(2-hydroxy-ethylamino)-2,3-dihydro-anthraquinone
- 3179-90-6
5,8-dihydroxy-1,4-bis<<2-hydroxyethyl>amino>-9,10-anthracenedione
| Conditions | Yield |
|---|---|
| With benzofurazan oxide In various solvent(s) at 70℃; for 16h; | 97% |
- 23478-60-6
leuco-1,4,5,8-tetrahydroxyanthraquinone
- 141-43-5
ethanolamine
- 3179-90-6
5,8-dihydroxy-1,4-bis<<2-hydroxyethyl>amino>-9,10-anthracenedione
| Conditions | Yield |
|---|---|
| With sodium dithionite; ethanol; boric acid Erhitzen des Reaktionsprodukts mit SOCl2 und Nitrobenzol; |
- 71924-08-8
1,4,5,8-tetrahydro-anthraquinone
- 141-43-5
ethanolamine
- 3179-90-6
5,8-dihydroxy-1,4-bis<<2-hydroxyethyl>amino>-9,10-anthracenedione
| Conditions | Yield |
|---|---|
| With sodium hydroxide; copper(II) sulfate |
- 81-59-4
1,4,5,8-tetrahydroxy-2,3-dihydro-9,10-anthracenedione
- 141-43-5
ethanolamine
- 3179-90-6
5,8-dihydroxy-1,4-bis<<2-hydroxyethyl>amino>-9,10-anthracenedione
| Conditions | Yield |
|---|---|
| (i) Me2NCH2CH2NMe2, (ii) PhNO2; Multistep reaction; |
| Conditions | Yield |
|---|---|
| With pyridine |
| Conditions | Yield |
|---|---|
| With air; water; boric acid | |
| anschliessende Oxydation; |
- 3179-90-6
5,8-dihydroxy-1,4-bis<<2-hydroxyethyl>amino>-9,10-anthracenedione
- 98-59-9
p-toluenesulfonyl chloride
- 111228-29-6
5,8-dihydroxy-1,4-bis<(2-p-toluensulfonyloxyethyl)amino>anthracene-9,10-dione
| Conditions | Yield |
|---|---|
| With pyridine for 4h; Ambient temperature; | 50% |
- 3179-90-6
5,8-dihydroxy-1,4-bis<<2-hydroxyethyl>amino>-9,10-anthracenedione
- 70476-82-3
novantrone
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 50 percent / pyridine / 4 h / Ambient temperature 2: 2.) hydrochloric acid / 1.) acetonitrile-DMA, 0.8 h, reflux, 2.) ether View Scheme |
- 3179-90-6
5,8-dihydroxy-1,4-bis<<2-hydroxyethyl>amino>-9,10-anthracenedione
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 50 percent / pyridine / 4 h / Ambient temperature 2: 2.) hydrochloric acid / 1.) DMA, 1.5 h, reflux, 2.) ether View Scheme |
Disperse Blue 7 Chemical Properties
Molecule structure of 5,8-Dihydroxy-1,4-dihydroxyethylamino-anthraquinone (CAS NO.3179-90-6) :
IUPAC Name: 1,4-dihydroxy-5,8-bis(2-hydroxyethylamino)anthracene-9,10-dione
Molecular Weight: 358.34532 g/mol
Molecular Formula: C18H18N2O6
Density: 1.607 g/cm3
Boiling Point: 757.4 °C at 760 mmHg
Flash Point: 411.8 °C
EINECS: 221-666-0
Appreance: fine black powder
Water Solubility: water soluble
Molar Volume: 222.8 cm3
Polarizability: 37.25*10-24 cm3
Surface Tension: 104.4 dyne/cm
Enthalpy of Vaporization: 115.77 kJ/mol
Vapour Pressure: 4.16E-24 mmHg at 25 °C
XLogP3-AA: 1.9
H-Bond Donor: 6
H-Bond Acceptor: 8
Rotatable Bond Count: 6
Tautomer Count: 90
Exact Mass: 358.116486
MonoIsotopic Mass: 358.116486
Topological Polar Surface Area: 139
Heavy Atom Count: 26
Complexity: 484
Canonical SMILES: C1=CC(=C2C(=C1NCCO)C(=O)C3=C(C=CC(=C3C2=O)O)O)NCCO
InChI: InChI=1S/C18H18N2O6/c21-7-5-19-9-1-2-10(20-6-8-22)14-13(9)17(25)15-11(23)3-4-12(24)16(15)18(14)26/h1-4,19-24H,5-8H2
InChIKey: WHPNHQRWWMLKPJ-UHFFFAOYSA-N
Disperse Blue 7 Toxicity Data With Reference
| 1. | msc-mus:lym 10 mg/L | EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EHQ-1179-0321 . | ||
| 2. | hma-mus:sat 8 g/kg | EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EHQ-1179-0321 . | ||
| 3. | ipr-rat LD50:700 mg/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 21 (12)(1977),27. |
Disperse Blue 7 Consensus Reports
Reported in EPA TSCA Inventory.
Disperse Blue 7 Safety Profile
Moderately toxic by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
Disperse Blue 7 Specification
5,8-Dihydroxy-1,4-dihydroxyethylamino-anthraquinone (CAS NO.3179-90-6) is also called 1,4-bis((2-hydroxyethyl)amino)-5,8-dihydroxy-anthraquinon ; 1,4-dihydroxy-5,8-bis((2-hydroxyethyl)amino)-10-anthracenedione ; 1,4-dihydroxy-5,8-bis((2-hydroxyethyl)amino)-9,10-anthracenedione ; 1,4-dihydroxy-5,8-bis((2-hydroxyethyl)amino)-anthraquinon ; 1,4-dioxyethylamino-5,8-dioxyanthraquinone ; 1,4-doea-5,8-dapfa ; 5,8-dihydroxy-1,4-dihydroxyethylaminoanthraquinone . 5,8-Dihydroxy-1,4-dihydroxyethylamino-anthraquinone (CAS NO.3179-90-6) is an amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Flash point data for 5,8-Dihydroxy-1,4-dihydroxyethylamino-anthraquinone (CAS NO.3179-90-6) are not available; however 5,8-Dihydroxy-1,4-dihydroxyethylamino-anthraquinone (CAS NO.3179-90-6) is probably combustible.
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