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Disulfur dinitride

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Name

Disulfur dinitride

EINECS N/A
CAS No. 25474-92-4 Density 2.22g/cm3
PSA 82.26000 LogP 0.59960
Solubility N/A Melting Point N/A
Formula N2S2 Boiling Point °Cat760mmHg
Molecular Weight 92.1454 Flash Point °C
Transport Information N/A Appearance N/A
Safety An explosive sensitive to shock, friction, pressure, or heating above 30°C. Potentially explosive reaction with complexes with beryllium chloride or titanium tetrachloride. When heated to decomposition it emits toxic fumes of SOx and NOx. See also NITRIDES. Risk Codes N/A
Molecular Structure Molecular Structure of 25474-92-4 (1$l^{4},3-dithia-2,4-diazacyclobuta-1,4-diene) Hazard Symbols N/A
Synonyms

1,3,2,4-Dithia(3-SIV)diazete(9CI); Nitrogen sulfide (N2S2); Sulfur nitride (S2N2) (6CI,7CI,8CI); Disulfurdinitride

Article Data 2

Disulfur dinitride Chemical Properties

Molecule structure of Disulfur dinitride (CAS NO.25474-92-4):

IUPAC Name: 2λ4,4-Dithia-1,3-diazacyclobuta-1,2-diene 
Molecular Weight: 92.1434 g/mol
Molecular Formula: N2S2 
Density: 2.22 g/cm3
Index of Refraction: 2.075
Molar Refractivity: 21.71 cm3
Molar Volume: 41.4 cm3
Polarizability: 8.61×10-24 cm3
Surface Tension: 123.5 dyne/cm
XLogP3-AA: 2.2
H-Bond Acceptor: 2
Exact Mass: 91.950289
MonoIsotopic Mass: 91.950289
Topological Polar Surface Area: 24.7
Heavy Atom Count: 4
Complexity: 42.1
Canonical SMILES: N1=S=NS1
InChI: InChI=1S/N2S2/c1-3-2-4-1
InChIKey: HGFWWXXKPBDJAH-UHFFFAOYSA-N

Disulfur dinitride Production

At low pressure (1mm Hg), passing gaseous S4N4 over silver metal wool at 250-300 °C  can yield cyclic S2N2. The silver reacts with the sulfur produced by the thermal decomposition of the S4N4 to form Ag2S, and the resulting Ag2S can catalyze the conversion of the S4N4 into the four-membered ring S2N2,
S4N4 + 8 Ag → 4 Ag2S + 2 N2
S4N4 → 2S2N2

Disulfur dinitride Safety Profile

An explosive sensitive to shock, friction, pressure, or heating above 30°C. Potentially explosive reaction with complexes with beryllium chloride or titanium tetrachloride. When heated to decomposition it emits toxic fumes of SOx and NOx. See also NITRIDES.

Disulfur dinitride Specification

 Disulfur dinitride (CAS NO.25474-92-4) will decompose explosively when the temperature is above 30°and it is sensitive by shock. It is insoluble in water, soluble in diethyl ether and traces of water cause it to polymerise into S4N4. Disulfur dinitride (CAS NO.25474-92-4) spontaneously polymerizes forming (SN)x in the solid state. It can form adducts with Lewis acids via a nitrogen atom, e.g. S2N2.BCl3, S2N2.2AlCl3, S2N2.SbCl5, S2N2.2SbCl5.

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