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Basic Information
CAS No.: 115-21-9
Name: Ethyltrichlorosilane
Molecular Structure:
Molecular Structure of 115-21-9 (Ethyltrichlorosilane)
Formula: C2H5Cl3Si
Molecular Weight: 163.506
Synonyms: Ethylsilicon trichloride;LS 120;SIE 4901.0;TSL 8226;Trichloroethylsilane;Trichloroethylsilicon;
EINECS: 204-072-6
Density: 1.244 g/cm3
Melting Point: -106 °C(lit.)
Boiling Point: 99.977 °C at 760 mmHg
Flash Point: 19.552 °C
Appearance: clear colorless liquid
Hazard Symbols: FlammableF, VeryT+
Risk Codes: 11-14-22-26-34
Safety: 26-28-36/37/39-45
Transport Information: UN 1196 3/PG 2
PSA: 0.00000
LogP: 2.66160
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Chemistry

IUPAC Name: Trichloro(ethyl)silane
The MF of Ethyltrichlorosilane (CAS NO.115-21-9) is C2H5Cl3Si.

                                
The MW of Ethyltrichlorosilane (CAS NO.115-21-9) is 163.51.
Synonyms of Ethyltrichlorosilane (CAS NO.115-21-9): Ethyl silicon trichloride ; Ethyl(trichloro)-silan ; Ethylsilicontrichloride ; Ethyltrichloro-silan
Product Categories: Functional Materials;Si (Classes of Silicon Compounds);Si-Cl Compounds;Silane Coupling Agents;Silane Coupling Agents (Intermediates);Trichlorosilanes
Apperance: clear colorless liquid
Index of Refraction: 1.439 
EINECS: 204-072-6
Density: 1.243 g/ml 
Flash Point: 19.6 °C
Boiling Point: 100 °C
Melting Point: -106 °C

Uses

  Ethyltrichlorosilane (CAS NO.115-21-9) is used as intermediate for manufacturing silicone.

Toxicity Data With Reference

1.    

skn-rbt 500 mg/24H MLD

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1220.
2.    

eye-rbt 250 µg/24H SEV

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1220.
3.    

ihl-rat LCLo:500 ppm/4H

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 31 (1949),343.
4.    

orl-rat LD50:1330 mg/kg

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 31 (1949),60.
5.    

ipr-rat LDLo:30 mg/kg

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 30 (1948),332.
6.    

ihl-mus LC50:300 µg/m3/2H

    TPKVAL    Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Sciences.(3),(1961),23.

Consensus Reports

EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.

Safety Profile

Poison by inhalation and intraperitoneal routes. Moderately toxic by ingestion. A skin and severe eye irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers; will react with water or steam to produce heat and toxic and corrosive fumes; can react vigorously with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of Cl and phosgene. See also CHLOROSILANES.Safety information of Ethyltrichlorosilane (CAS NO.115-21-9):
Hazard Codes  FlammableF,VeryT+
Risk Statements 
11 Highly Flammable
14 Reacts violently with water
22 Harmful if swallowed
26 Very Toxic by inhalation
34 Causes burns
Safety Statements 
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR  UN 1196 3/PG 2
WGK Germany  1
RTECS  VV4200000
F  19-21
TSCA  Yes
HazardClass  3.1
PackingGroup  II

Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid, Corrosive

Specification

Chlorosilanes, such as Ethyltrichlorosilane, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.