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FURIL

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FURIL

EINECS 207-766-7
CAS No. 492-94-4 Density 1.302 g/cm3
PSA 60.42000 LogP 1.93820
Solubility Slight solubility in water Melting Point 163-165ºC
Formula C10H6 O4 Boiling Point 302.7 ºC at 760 mmHg
Molecular Weight 190.155 Flash Point 138.4ºC
Transport Information N/A Appearance White crystal or powder. Odorless.
Safety Poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating fumes. Risk Codes N/A
Molecular Structure Molecular Structure of 492-94-4 (Furil) Hazard Symbols N/A
Synonyms

Ethanedione,di-2-furanyl- (9CI);Furil (6CI,7CI,8CI);1,2-Di(2-furyl)ethanedione;1,2-Di(furan-2-yl)ethane-1,2-dione;1,2-Di-2-furylethane-1,2-dione;2,2'-Furil;Bipyromucyl;Difuranylglyoxal;NSC 5561;a-Furil;

Article Data 114

FURIL Chemical Properties

IUPAC Name: 1,2-bis(Furan-2-yl)ethane-1,2-dione
Synonyms: 1,2-Di(2-Furyl)-1,2-ethanedione ; 1,2-Di(furan-2-yl)ethan-1,2-dion ; 1,2-Di(Furan-2-yl)ethane-1,2-dione ; 1,2-Di-2-Furylethane-1,2-dione ; 1,2-Ethanedione, 1,2-di-2-furanyl-
Molecular Structure of Furil (CAS NO.492-94-4) :
Molecular Formula of Furil (CAS NO.492-94-4) : C10H6O4
Molecular Weight of Furil (CAS NO.492-94-4) : 190.15
CAS NO: 492-94-4
EINECS : 207-766-7
Index of Refraction: 1.54
Surface Tension: 46.4 dyne/cm
Density: 1.302 g/cm3
Flash Point: 138.4 °C
Enthalpy of Vaporization: 54.3 kJ/mol
Boiling Point: 302.7 °C at 760 mmHg
Vapour Pressure: 0.000971 mmHg at 25°C
Melting point 163-165 ºC
Appearance:yellow-brown crystalline powder
Solubility: soluble in methanol, chloroform, benzene and hot alcohol, insoluble in cold ethanol and ether, insoluble in water.

FURIL Uses

 Furil (CAS NO.492-94-4) is used in organic synthesis.

FURIL Production

 Furil (CAS NO.492-94-4) is obtained from furfural. Furfural with the catalytic potassium cyanide, condensation reaction with asymmetric benzoin to get 2-Hydroxy ethyl ketone flavor furans. Then oxidation,obtaining Furil.Adding Lead sulfate 158g (including the five crystal water), 210g pyridine, 90g water, mixing with heated water bath into a homogeneous solution, then add 57.6g Furoin, after 2h stirring in heated water bath,then adding into the 1L of cold water, precipitation of crystallization, filtration, wash, ethanol wash. then recrystallized by Ethanol, Furil is derived .

FURIL Toxicity Data With Reference

1.    

ivn-mus LD50:56 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#03858 .

FURIL Consensus Reports

Reported in EPA TSCA Inventory.

FURIL Safety Profile

Poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating fumes.
Safety Statements 24/25
S24/25:Avoid contact with skin and eyes.
WGK Germany 3
RTECS LV0580000

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