Stereochemistry and Conformation of a Nitrogen-Containing, Medium-Sized Ring: Hexahydro-1-phenyl-3-benzazonine Derivatives. High 1,4-Diastereoselectivity in Hydrogenation of an Exocyclic Alkene

DOI: 10.1021/jo00367a009

Source and publish data:

Journal of Organic Chemistry p. 3295 - 3302 (1986)

Update date:2022-09-26

Topics:

Authors:

Maryanoff, Bruce E.

Almond, Harold R.

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Article abstract of DOI:10.1021/jo00367a009

Hydrogenation of olefin 2 or 4 (as a perchlorate salt) over platinum afforded in each case almost exclusively (at least 95percent) one diastereomeric, saturated product, 3 or 5, respectively.The other diastereomer corresponding to 5 was obtained by sodium

Full text of DOI:10.1021/jo00367a009

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