Synthesis p. 1063 - 1064 (1993)
Update date:2022-08-04
Topics:
Martinez, A. Garcia
Fernandez, A. Herrera
Alvarez, R. Martinez
Barcina, J. Osio
Gomez, C. Garcia
Subramanian, L. R.
gem-Dialkylation or alkylative reduction of α-unbranched aliphatic aldehydes is easily carried out by replacing the carbonyl oxygen with the gem-dihalide functionality followed by substitution of each halogen (bromine or iodine) by two n-alkyl groups or one sec- or tert-alkyl group and one hydrogen atom using higher-order dialkyl-lithium cyanocuprates.
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Doi:10.1007/BF00564154
()Doi:10.1002/ardp.19793120711
(1979)Doi:10.1021/jo01293a009
(1980)Doi:10.1021/jo01299a039
(1980)Doi:10.1248/cpb.27.2675
(1979)Doi:10.1021/jo01305a006
(1980)
