Tetrahedron Letters p. 1619 - 1622 (2008)
Update date:2022-08-04
Topics:
Shinozuka, Tsuyoshi
Yamamoto, Yuko
Hasegawa, Toru
Saito, Keiji
Naito, Satoru
The first total synthesis of sterenins A, C and D, potent inhibitors of 11β-hydroxysteroid dehydrogenase type 1 (11β-HSD1), is described. The prenyl group was regioselectively introduced by a Claisen rearrangement, whereas the construction of an isoindolinone skeleton was accomplished by the lactamization of lactones assisted by a phenolic hydroxyl group.
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