Ethynyltriisopropoxytitanium reactions with pyrimidinones

DOI: 10.1016/0022-328X(88)80007-X

Source and publish data:

Journal of Organometallic Chemistry p. 341 - 346 (1988)

Update date:2022-07-29

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Authors:

Rise, Frode

Grace, David

Undheim, Kjell

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Article abstract of DOI:10.1016/0022-328X(88)80007-X

Ethynyltriisopropoxytitanium has beem generated in situ from ethynyllithium and chlorotriisopropoxytitanium at -80 deg C.It forms 1/1 adducts with pyrimidin-2(1H)-ones with exclusive carbon-carbon bond formation at C(6).The products after quenching ethyny

Full text of DOI:10.1016/0022-328X(88)80007-X

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