
Journal of Organic Chemistry p. 2505 - 2511 (1986)
Update date:2022-08-04
Topics:
Pearson, Anthony J.
Hsu, Shih-Ying
Construction of potential key intermediate 3b for trichothecene synthesis is explored, on the basis of an ester-assisted alkene functionalization, which leads to a short synthesis of lactone 3a.Evaluation of the directing effect of ester functionality on epoxidation of a neighboring double bond was carried out by using a number of cyclohexene and cycloheptene derivatives.
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