Reaction of Sulfonium Salts of Formaldehyde Dithioacetals with Aromatic Aldehydes and Rearrangements of the Produced Thioalkyl Oxiranes

DOI: 10.1016/0040-4020(95)00632-I

Source and publish data:

Tetrahedron p. 10593 - 10600 (1995)

Update date:2022-07-30

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Authors:

Makosza, Mieczyslaw

Sypniewski, Michal

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Article abstract of DOI:10.1016/0040-4020(95)00632-I

Aromatic aldehydes react with sulfur ylides generated from sulfonium salts of formaldehyde dithioacetals to give corresponding 2-thioalkyl-3-aryloxiranes.Depending on substituents in aromatic rings the oxiranes undergo rearrangements or are sufficiently stable to be isolated.

Full text of DOI:10.1016/0040-4020(95)00632-I

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