Reaction of Sulfonium Salts of Formaldehyde Dithioacetals with Aromatic Aldehydes and Rearrangements of the Produced Thioalkyl Oxiranes

DOI: 10.1016/0040-4020(95)00632-I

Source and publish data:

Tetrahedron p. 10593 - 10600 (1995)

Update date:2022-07-30

Topics:

Authors:

Makosza, Mieczyslaw

Sypniewski, Michal

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)00632-I

Aromatic aldehydes react with sulfur ylides generated from sulfonium salts of formaldehyde dithioacetals to give corresponding 2-thioalkyl-3-aryloxiranes.Depending on substituents in aromatic rings the oxiranes undergo rearrangements or are sufficiently stable to be isolated.

Full text of DOI:10.1016/0040-4020(95)00632-I

Products guided by the article

Product name:iodomethyl 4-chlorophenyl sulfide

Cas No:102618-23-5

R&D Labs maybe for 102618-23-5

Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
JIANGXI ZHANGFENG CHEMICAL CO., LTD.

Contact:+86-0799-3413066

Address:Xiyuan village, Xiabu Town, Xiangdong District
Zha Yan

Contact:+86-13914766747

Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing

Relevant to this article

Synthesis of novel O,P,C-cage complexes via thermal C-O ring opening of an oxaphosphirane W(CO)₅ complex

Doi:10.1021/om7012953
(2008)
Photoinduced coupled charge and proton transfers in gradually twisted phenol-pyridinium biaryl series

Doi:10.1021/jp904601r
(2010)
Tricyclic Quinoxalinediones: 5,6-Dihydro-1H-pyrrolo<1,2,3-de>quinoxaline-2,3-diones and 6,7-Dihydro-1H,5H-pyrido<1,2,3-de>quinoxaline-2,3-diones as Potent Antagonists for the Glycine Binding Site of the NMDA Receptor

Doi:10.1021/jm00049a015
(1994)
Structure-activity relationship of N-[2-(dimethylamino)-6-[3-(5-methyl-4- phenyl-1H-imidazol-1-yl)propoxy]phenyl]-N'-pentylurea and analogues. Novel potent inhibitors of acyl-CoA:cholesterol O-acyltransferase with antiatherosclerotic activity

Doi:10.1021/jm00063a013
(1993)
Trapping of a chromophoric intermediate in the Pdx1-catalyzed biosynthesis of pyridoxal 5′-phosphate

Doi:10.1002/anie.200704390
(2008)
InBr₃-promoted divergent approach to polysubstituted indoles and quinolines from 2-ethynylanilines: Switch from an intramolecular cyclization to an intermolecular dimerization by a type of terminal substituent group

Doi:10.1021/jo800464u
(2008)

Article Doi