Synthesis and some transformations of 1,2-heterophosphacyclanes

Article abstract of DOI:10.1080/10426509908546308

The general pathway to 1,2-monoheterophosphacyclanes via intramolecular S-and N-alkylation of ω-halogenoalkylsubstituted thiophosphoryl and iminophosphoryl compounds has been developed. Intramolecular alkylation of 3-and 4-halogenoalkyldiphenylphosphine sulfides results in 1,2λ⁴-thiaphospholanium and thiaphosphorinanium halogenides. In solution of these compounds the rare ring-chain halogenotropic tautomerism has been observed and investigated in detail. Intramolecular Pishchimuka rearrangement of the esters of ω-halogenoalkylsubstituted thiophosphorus acids was found to be a synthetic route to 2-oxo-1,2ω⁵-thiaphospholanes and thiaphosphorinanes.

Full text of DOI:10.1080/10426509908546308

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Phosphorus, Sulfur, and
Silicon and the Related
Elements
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Synthesis and Some
Transformations of 1,2-
Heterophosphacyclanes
Tatyana A. Mastryukova , Inga M.
Aladzheva , Dmitrii I. Lobanov , Olga
V. Bykhovskaya , Pavel V. Petrovskii ,
Konstantin A. Lyssenko & Martin I.
Kabachnik
a A.N. Nesmeyanov Institute of
Organoelement Compounds, Russian
Academy of Sciences , Vavilova, 28,
117813 Moscow, Russia
b A.N. Nesmeyanov Institute of
Organoelement Compounds, Russian
Academy of Sciences , Vavilova, 28,
117813 Moscow, Russia
c A.N. Nesmeyanov Institute of
Organoelement Compounds, Russian
Academy of Sciences , Vavilova, 28,
117813 Moscow, Russia
d A.N. Nesmeyanov Institute of
Organoelement Compounds, Russian
Academy of Sciences , Vavilova, 28,
117813 Moscow, Russia

e A.N. Nesmeyanov Institute of
Organoelement Compounds, Russian
Academy of Sciences , Vavilova, 28,
117813 Moscow, Russia
f A.N. Nesmeyanov Institute of
Organoelement Compounds, Russian
Academy of Sciences , Vavilova, 28,
117813 Moscow, Russia
g A.N. Nesmeyanov Institute of
Organoelement Compounds, Russian
Academy of Sciences , Vavilova, 28,
117813 Moscow, Russia
Published online: 17 Mar 2008.
To cite this article: Tatyana A. Mastryukova , Inga M. Aladzheva , Dmitrii
I. Lobanov , Olga V. Bykhovskaya , Pavel V. Petrovskii , Konstantin A.
Lyssenko & Martin I. Kabachnik (1999) Synthesis and Some Transformations
of 1,2-Heterophosphacyclanes, Phosphorus, Sulfur, and Silicon and the
Related Elements, 144:1, 569-572, DOI: 10.1080/10426509908546308
To link to this article: http://dx.doi.org/10.1080/10426509908546308
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