The Preparation and Crystal Structure of the Unusual Copper-Sulphur Cage Complex Cu8(SC5H11)4(S2CSC5H11)4

DOI: 10.1039/c39860000188

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Journal of the Chemical Society. Chemical communications p. 188 - 189 (1986)

Update date:2022-08-05

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Authors:

Chadha, R.

Kumar, Rajesh

Tuck, Dennis G.

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Article abstract of DOI:10.1039/c39860000188

The electrochemical oxidation of anodic copper in an acetonitrile solution of RSH (R = Ph, C10H7, CPh3, C6F4H, o-MeC6H4, CMe2Et) yields CuSR; treatment of CuSCMe2Et with CS2 produces Cu8(SR)4(S2CSR)4, whose structure is based on an unusual Cu8S12 cage.

Full text of DOI:10.1039/c39860000188

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