Journal of Physical Chemistry p. 4691 - 4694 (1986)
Update date:2022-08-03
Topics:
Gaspar, Peter P.
Berowitz, David M.
Strongin, Daniel R.
Svoboda, Daniel L.
Tuchler, Matthew B.
et al.
Formation of benzocyclobutene, a characteristic rearrangement product of tolylmethylenes, strongly suggest that these species are formed as intermediates in the reactions of recoiling carbon-11 atoms and toluene.Degradation and additive studies indicated that both singlet and triplet carbon atoms can lead to benzocyclobutene formation through insertion into ring C-H bonds.Styrene is also formed, predominantly by insertion of singlet C-11 atoms into a methyl C-H bond, followed by rearrangement of the resulting benzylmethylene.
View MoreForsman Scientific(Beijing)co.,Ltd.
Contact:+86-10-64646565
Address:Rm No.1301, Building-2, No. A-13 Beiyuan Road, Chaoyang District Beijing, China, PR,
Contact:+31-24-3886056
Address:Binderskampweg 29 Unit 36
Yixing Zhenfen Medical Chemical Co.Ltd
Contact:86-510-87552708
Address:Fenshui ,Yixing city,Jiangsu
Anhui Asahikasei Chemical Co., Ltd
Contact:86-551-4259770
Address:No. 88 Linquan Road Hefei Anhui China
Hangzhou Dingyan Chem Co., Ltd
website:http://www.dingyanchem.com
Contact:86-571-87157530
Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Doi:10.1021/om800141y
(2008)Doi:10.1021/jm00161a005
(1986)Doi:10.1016/j.tetlet.2008.04.076
(2008)Doi:10.1021/ja01539a035
(1958)Doi:10.1021/np800185k
(2008)Doi:10.1016/j.saa.2007.10.054
(2008)
