A New Synthesis of Eight-membered Lactones containing a 5,6-Double Bond

DOI: 10.1039/c39860000325

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 325 - 326 (1986)

Update date:2022-08-04

Topics:

Authors:

Carling, Robert W.

Holmes, Andrew B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39860000325

Claisen rearrangement of the vinyl ketene acetals (7; a, R = CH2OSiPh2t-Bu, or b, R = n-pentyl) which are generated in situ by syn-elimination of the corresponding selenoxides (6a,b) in refluxing xylene gave the eight-membered lactones (8a,b).

Full text of DOI:10.1039/c39860000325

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4-Pentyl-2-phenylselanylmethyl-6-vinyl-[1,3]dioxane

Cas No:104085-41-8

R&D Labs maybe for 104085-41-8

Xinyanhe Pharmatech Co.,Ltd

Contact:+86-519-8525-2752

Address:Changzhou
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang
Jiangxi Huashi Pharmaceutical Co., Ltd

Contact:+86-795-4509628

Address:No.199, Ningbo Avenue, Fengxin industrial park, Fengxin county, Yichun city, Jiangxi
Yantai Derun Liquid Crystal Materials Co. Ltd.

website:http://www.ytderun.com

Contact:86-535-6300169

Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI

Relevant to this article

Cleavage of carbon-carbon bonds in alkyl cyanides using nickel(0)

Doi:10.1021/om049700t
(2004)
The reaction of phthalidylidene dichloride with primary amines. Synthesis and X-ray molecular structure of N-substituted phthalisoimides

Doi:10.1016/S0040-4020(97)00194-4
(1997)
Antioxidant study and assignments of NMR spectral data for 3′,4′,7-trihydroxyflavanone 3′,7-Di-O-β-D-glucopyranoside (butrin) and its hydrolyzed product

Doi:10.1023/B:CONC.0000039134.46227.1f
(2004)
Ring transformation of 4-amino-1H-1,5-benzodiazepine-3-carbonitrile. The use of hydroxylamines as nucleophile

Doi:10.1248/cpb.28.567
(1980)
Hydrozirconation of Thioketones. A Simple, Convenient Entry into a Variety of Organosulfur Compounds. An Intersting Ether Synthesis

Doi:10.1021/jo00315a012
(1981)
Syntheses and immunoadjuvant activity of some carbohydrate analogs of N-acetylmuramyl-L-alanyl-D-isoglutamine

Doi:10.1080/00021369.1980.10864112
(1980)

Article Doi