STEREOCHEMICAL INVESTIGATION OF THE REACTION OF CYCLOPENTADIENYL(DIPHOSPHINE)METHOXYCARBENERUTHENIUM(II) COMPLEXES WITH LiAlH4

DOI: 10.1016/0022-328X(85)80310-7

Source and publish data:

Journal of Organometallic Chemistry p. C29 - C32 (1985)

Update date:2022-08-04

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Authors:

Consiglio, Giambattista

Bangerter, Felix

Morandini, Franco

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Article abstract of DOI:10.1016/0022-328X(85)80310-7

<(η-C5H5)Ru>PF6 (where R, R'=H or CH3) reacts with LiAlH4 in THF at -80 deg C to give the corresponding 2-phenylethyl complexes, which have antiperiplanar conformation around the H2C-CH2 bond in solution; the reaction take

Full text of DOI:10.1016/0022-328X(85)80310-7

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Product name:(C₅H₅)Ru((C₆H₅)2PCH(CH₃)CH(CH₃)P(C₆H₅)2)C⁽²⁾H₂CH₂C₆H₅

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