Tetrahedron Letters p. 1987 - 1990 (1986)
Update date:2022-08-03
Topics:
Schmidtchen, F. P.
The synthetic strategy to connect two macrotricyclic ammonium salts of different sizes (1,2) to give the ditopic receptor 9 is described.A host-guest complexation analysis reveals that the binding of 13 in contrast to the analogues 10-12 involves interactions with either tetrahedral subsite of 9.The ditopic receptor 9 discriminates between 12 and 13 by a factor of 3 relative to the monotopic host 2.
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