Organometallics p. 421 - 423 (1987)
Update date:2022-08-04
Topics:
Arvanitis, Georgia M.
Schwartz, Jeffrey
The reaction between Zr(IV) metalloazines and aldehydes affords unsymmetrical olefins and azines. Relative rates for formation of these species (and corresponding yields) were found to depend on the electron-donating ability of the metalloazine and on the electron-accepting ability of the aldehyde. Second-order rate constants were determined, and a reaction mechanism for olefin synthesis is proposed based on observed electronic effects.
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Doi:10.1039/b806816j
(2008)Doi:10.1021/acs.joc.0c00983
(2020)Doi:10.1016/S0040-4039(00)85023-6
(1986)Doi:10.1016/j.bmcl.2006.12.116
(2007)Doi:10.1002/adsc.200800091
(2008)Doi:10.1016/S0040-4020(01)87683-3
(1987)
