Journal of Organometallic Chemistry p. 301 - 308 (1986)
Update date:2022-07-30
Topics:
Ito, Yoshihiko
Kobayashi, Kazuhiro
Saegusa, Takeo
Substituted o-methylphenyl isocyanides (1) were oxidatively dimerized via the corresponding o-lithiomethylphenyl isocyanides (2) by means of 1,2-dibromoethane to give 1,2-bis(2-isocyanophenyl)ethane derivatives (3). 1,2-Bis(2-isocyano-3-methylphenyl)ethane (3e), a coupling dimer of 2,6-xylyl isocyanide (1e), was further dimerized via its dilithiated intermediate to give a cyclic tetramer of 2,6-xylyl isocyanide (1e), which may be a cyclic tetradentate ligand for transition metal compounds.
View MoreContact:+86 021-51698675
Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD
website:http://www.jinjingroup.com
Contact:4009982989
Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Contact:+86-710-3516804
Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei
Yicheng Goto Pharmaceuticals Co.,Ltd.
Contact:+86 710 3423122
Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China
Nanjing Yuance Industry&Trade Co., Ltd.
website:http://www.njyuance.cn/
Contact:+86-25-85439097
Address:B1702, Aoti Bldg, No. 130, Aoti Avenue, Nanjing, China
Doi:10.1039/c2cc31438j
(2012)Doi:10.1021/ja9931832
(1999)Doi:10.1039/jr9480001106
(1948)Doi:10.1021/jacs.9b10217
(2019)Doi:10.1021/jo00835a057
(1970)Doi:10.1002/1521-3765(20020703)8:13<2946::AID-CHEM2946>3.0.CO;2-M
(2002)