Journal of Organometallic Chemistry p. 301 - 308 (1986)
Update date:2022-07-30
Topics:
Ito, Yoshihiko
Kobayashi, Kazuhiro
Saegusa, Takeo
Substituted o-methylphenyl isocyanides (1) were oxidatively dimerized via the corresponding o-lithiomethylphenyl isocyanides (2) by means of 1,2-dibromoethane to give 1,2-bis(2-isocyanophenyl)ethane derivatives (3). 1,2-Bis(2-isocyano-3-methylphenyl)ethane (3e), a coupling dimer of 2,6-xylyl isocyanide (1e), was further dimerized via its dilithiated intermediate to give a cyclic tetramer of 2,6-xylyl isocyanide (1e), which may be a cyclic tetradentate ligand for transition metal compounds.
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