Tetrahedron Letters p. 1039 - 1042 (1986)
Update date:2022-07-29
Topics: Cross-Coupling Reactions Functional Group Transformations Redox Reactions Catalytic Activity Metal Insertion Reduction of Metal-Metal Bonds Use of Metal-Carbene Complexes Chelation and Coordination Chemistry
Knochel, P.
Normant, J. F.
A number of gem-dimetallic compounds 4a-i have been prepared by carbometallation of an alkenyl organometallic derivative of Mg, Li or Al by an allylic zinc bromide.The 1-magnesia-1-zincaalkenes 4a-b react smoothly with various aldehydes in the presence of
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(1987)