Organic and Biomolecular Chemistry p. 2884 - 2891 (2008)
Update date:2022-07-31
Topics:
Pesnot, Thomas
Wagner, Gerd K.
A series of novel 5-substituted UDP-glucose derivatives with interesting fluorescent properties and potential applications as sensors for carbohydrate-active enzymes is reported. An efficient synthesis of the target molecules was developed, centred around the Suzuki-Miyaura reaction of (hetero)arylboronic acids with 5-iodo UDP-glucose. Interestingly, the optimised cross-coupling conditions could also be applied successfully to 5-bromo UMP, but not to 5-bromo UDP-glucose. The Royal Society of Chemistry.
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Doi:10.1039/b804294b
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(2008)