Journal of Organic Chemistry p. 1047 - 1051 (1987)
Update date:2022-08-04
Topics: Stereoselective Nitrile Cycloaddition Experimental terms Nitrone
Plate, Ralf
Hermkens, Pedro H. H.
Smits, Jan M. M.
Nivard, Rutger J. F.
Ottenheijm, Haary C. J.
The cycloaddition of the nitrones 8-11 to the geminal dinitriles 12a-d has been evaluated.Under thermal as well high-pressure reaction conditions 1,3 dipolar cycloadditions proceed with complete regioselectivity to give the Δ4-1,2,4-oxadiazolin
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(1955)