Synthesis of C-Disaccharides

DOI: 10.1021/jo00383a045

Source and publish data:

Journal of Organic Chemistry p. 1370 - 1372 (1987)

Update date:2022-08-03

Topics:

Authors:

Babirad, Stefan A.

Wang, Yuan

Kishi, Yoshito

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Article abstract of DOI:10.1021/jo00383a045

Stereocontrolled syntheses of four C-disaccharides 10, 11, 16, and 17 were reported.The (n-Pr)3SiH/BF3*Et2O reduction of hemiketals such as 7 yielded the equatorially substituted C-glycoside as the major product while C-alkylation (CH<*>CCH2Si(CH3)3/BF3*E

Full text of DOI:10.1021/jo00383a045

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