Journal of Organic Chemistry p. 1370 - 1372 (1987)
Update date:2022-08-03
Topics:
Babirad, Stefan A.
Wang, Yuan
Kishi, Yoshito
Stereocontrolled syntheses of four C-disaccharides 10, 11, 16, and 17 were reported.The (n-Pr)3SiH/BF3*Et2O reduction of hemiketals such as 7 yielded the equatorially substituted C-glycoside as the major product while C-alkylation (CH<*>CCH2Si(CH3)3/BF3*E
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(1959)