Bulletin of the Chemical Society of Japan p. 1629 - 1631 (1986)
Update date:2022-09-26
Topics:
Saito, Norio
Hatakeda, Kiyotaka
Ito, Shota
Asano, Takashi
Reactions of 2-methoxy-3,3-dimethyl-2-phenyloxirane or α-bromoisobutyrophenone and carbon dioxide in the presence of aliphatic α,ο-diamines were investigated. 1,4-Butanediamine, 1,6-hexanediamine, 1,8-octanediamine, and 1,4-bis(aminomethyl)benzene afforded corresponding 3-(ο-aminoalkyl)-4-hydroxy-5,5-dimethyl-4-phenyl-2-oxazolidinones and 3,3'-polymethylenebis<4-hydroxy-5,5-dimethyl-4-phenyl-2-oxazolidinones> derivatives, while ethylene-diamine gave only mono-(2-oxazolidinone) derivative.
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