Angewandte Chemie - International Edition p. 14955 - 14958 (2019)
Update date:2022-09-26
Topics:
Dommaschk, Marcel
Echavarren, Javier
Leigh, David A.
Marcos, Vanesa
Singleton, Thomas A.
We report on a switchable rotaxane molecular shuttle that features a pseudo-meso 2,5-disubstituted pyrrolidine catalytic unit on the axle whose local symmetry is broken according to the position of a threaded benzylic amide macrocycle. The macrocycle can
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