CHLORIDE-BRIDGED METHYLPALLADIUM(II) DIMERS. PREPARATION, CARBONYLATION AND BRIDGE-SPLITTING REACTIONS WITH TERTIARY PHOSPHINES

DOI: 10.1016/S0022-328X(00)99667-0

Source and publish data:

Journal of Organometallic Chemistry p. 127 - 134 (1986)

Update date:2022-07-29

Topics: Preparation Carbonylation Tertiary Phosphines

Authors:

Hayashi, Yoshihito

Isobe, Kiyoshi

Nakamura, Yukio

Okeya, Seichi

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Article abstract of DOI:10.1016/S0022-328X(00)99667-0

(L=PEt3, PBu3 or PMe2Ph) reacts with AlMe3 in ether, THF or a mixture of these solvents depending on L to give in high yield, which has been characterized by IR and NMR spectroscopy as well as elemental analysis.Treatment of with CO yields , while its reaction with L leads to trans-.The preparative method and the characteristic data of these complexes are discussed in comparison with the earlier work on the analogous aryl and aralkyl complexes.

Full text of DOI:10.1016/S0022-328X(00)99667-0

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