CHLORIDE-BRIDGED METHYLPALLADIUM(II) DIMERS. PREPARATION, CARBONYLATION AND BRIDGE-SPLITTING REACTIONS WITH TERTIARY PHOSPHINES

DOI: 10.1016/S0022-328X(00)99667-0

Source and publish data:

Journal of Organometallic Chemistry p. 127 - 134 (1986)

Update date:2022-07-29

Topics: Preparation Carbonylation Tertiary Phosphines

Authors:

Hayashi, Yoshihito

Isobe, Kiyoshi

Nakamura, Yukio

Okeya, Seichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)99667-0

(L=PEt3, PBu3 or PMe2Ph) reacts with AlMe3 in ether, THF or a mixture of these solvents depending on L to give in high yield, which has been characterized by IR and NMR spectroscopy as well as elemental analysis.Treatment of with CO yields , while its reaction with L leads to trans-.The preparative method and the characteristic data of these complexes are discussed in comparison with the earlier work on the analogous aryl and aralkyl complexes.

Full text of DOI:10.1016/S0022-328X(00)99667-0

Products guided by the article

Product name:Pd₂(Cl)2(CH₃)2(P(CH₃)2(C₆H₅))2

Cas No:107604-11-5

R&D Labs maybe for 107604-11-5

Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
Suzhou CarbonWell Pharma-Tech Co., Ltd

Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602

Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing
Shandong Shouguang Songchuan Industrial Additives Co.,Ltd

Contact:+86-536-8566856

Address:Shouguang,Shandong,China
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada

Relevant to this article

SITE SELECTIVE CYCLOADDITION REACTION OF 1-METHOXY-1-TRIMETHYLSILOXY-1,3,5-HEXATRIENE WITH DIENOPHILE

Doi:10.1016/S0040-4039(00)84801-7
(1986)
Tunable emissive thin films through ICT photodisruption of nitro-substituted triarylamines

Doi:10.1039/c001122c
(2010)
SYNTHESIS OF 5-AMINO-2-CYANO-4-SILYLPYRROLES FROM SILYLACETYLENES AND TRIMETHYLSILYL CYANIDE

Doi:10.1016/S0040-4039(00)84948-5
(1986)
A 1,3-Dipolar Cycloaddition Route to the 3(R)- and 3(S)-Hydroxy-(2S)-arginines

Doi:10.1021/jo00387a012
(1987)
Spectroscopic detection of iminocyclophosphamide and its possible role in cyclophosphamide metabolism

Doi:10.1021/jm00389a024
(1987)
Stereoselective synthesis and absolute configuration of epoxyketones in chlamydocin and related cyclic tetrapeptides

Doi:10.1016/S0040-4039(00)84399-3
(1986)

Article Doi