SYNTHESIS OF 5-AMINO-2-CYANO-4-SILYLPYRROLES FROM SILYLACETYLENES AND TRIMETHYLSILYL CYANIDE

DOI: 10.1016/S0040-4039(00)84948-5

Source and publish data:

Tetrahedron Letters p. 4197 - 4200 (1986)

Update date:2022-07-29

Topics:

Authors:

Kusumoto, Tetsuo

Hiyama, Tamejiro

Ogata, Koreharu

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Article abstract of DOI:10.1016/S0040-4039(00)84948-5

The reaction of silylacetylenes with trimethylsilyl cyanide in the presence of palladium catalysts gives 3-substituted 5-(N,N-bis(trimethylsilyl)amino)-2-cyano-4-silylpyrroles with high regioselectivity.

Full text of DOI:10.1016/S0040-4039(00)84948-5

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