SITE SELECTIVE CYCLOADDITION REACTION OF 1-METHOXY-1-TRIMETHYLSILOXY-1,3,5-HEXATRIENE WITH DIENOPHILE

DOI: 10.1016/S0040-4039(00)84801-7

Source and publish data:

Tetrahedron Letters p. 3381 - 3384 (1986)

Update date:2022-07-29

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Authors:

Ohno, Masatomi

Mori, Kohki

Eguchi, Shoji

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Article abstract of DOI:10.1016/S0040-4039(00)84801-7

The Diels-Alder reaction of the title triene occurred at the site of C-3-C-6 rather than of intuitively favored C-1-C-4, as the result of the prevailing steric effect over the orbital effect.

Full text of DOI:10.1016/S0040-4039(00)84801-7

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