OXIRANYLIDENE INTERMEDIATE IN THE REACTION OF TRANS-2-CHLORO-3-TERT-BUTYLOXIRANE WITH SODIUM PHENOXIDE

DOI: 10.1016/S0040-4039(00)84962-X

Source and publish data:

Tetrahedron Letters p. 4399 - 4402 (1986)

Update date:2022-08-05

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Authors:

Goering, Harlan L.

Paisley, Steven D.

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Article abstract of DOI:10.1016/S0040-4039(00)84962-X

The reaction of trans-2-chloro-3-(t-butyl)oxirane with sodium phenoxide in acetonitrile to give trans-2-phenoxy-3-(t-butyl)oxirane involves α-elimination to give an oxiranylidene which undergoes a stereoselective stepwise addition of phenol to give produc

Full text of DOI:10.1016/S0040-4039(00)84962-X

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