Chemistry of Oxaziridines. 8. Asymmetric Oxidation of Nonfunctionalized Sulfides to Sulfoxides with High Enantioselectivity by 2-Sulfamyloxaziridines. The Influence of the Oxaziridine C-Aryl Group on the Asymmetric Induction

DOI: 10.1021/ja00245a030

Source and publish data:

Journal of the American Chemical Society p. 3370 - 3377 (1987)

Update date:2022-07-29

Topics: Enantioselectivity Sulfides Asymmetric Oxidation Oxaziridines Sulfoxides

Authors:

Davis, Franklin A.

McCauley, John P.

Chattopadhyay, Sankar

Harakal, Mark E.

Towson, James C.

et al. et al.

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Article abstract of DOI:10.1021/ja00245a030

Chiral sulfamyloxaziridines 6 and 7, prepared by biphasic oxidation of the corresponding sulfamylimines 5, afford high asymmetric induction for the oxidation of a series of nonfunctionalized sulfides to sulfoxides (53-91percent ee).The enantioselectivitie

Full text of DOI:10.1021/ja00245a030

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