Angewandte Chemie - International Edition p. 8036 - 8039 (2008)
Update date:2022-07-30
Topics:
Barrell, Michael J.
Leigh, David A.
Lusby, Paul J.
Slawin, Alexandra M. Z.
(Chemical Equation Presented) Chloride control: The serendipitous discovery of a molecular recognition motif that is triggered by the formation of an anion-palladium coordination bond is exploited as an efficient rotaxane-forming template and as the basis of a molecular shuttle. The macrocycle of this rotaxane moves between the two stations when the counterion is changed from chloride to hexafluorophosphate (see picture).
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