
Journal of the Chemical Society. Perkin transactions I p. 61 - 70 (1994)
Update date:2022-07-29
Topics: Characterization Yield Catalysts Reagents Total synthesis Purification Starting Materials Stereoselectivity
Leonard, John
Hussain, Nigel
(+/-)-Specionin has been synthesized in a short, efficient sequence of reactions from (+/-)-exo,exo-6,7-bis(benzyloxy)-exo-4-(hydroxymethyl)-cis-bicyclo<3.3.0>oct-2-ene 5.The key feature of the synthesis is a 'one-pot' hydrogenolysis-cyclopentadienol clea
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