Total Synthesis of (+/-)-Specionin

DOI: 10.1039/P19940000061

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 61 - 70 (1994)

Update date:2022-07-29

Topics: Characterization Yield Catalysts Reagents Total synthesis Purification Starting Materials Stereoselectivity

Authors:

Leonard, John

Hussain, Nigel

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Article abstract of DOI:10.1039/P19940000061

(+/-)-Specionin has been synthesized in a short, efficient sequence of reactions from (+/-)-exo,exo-6,7-bis(benzyloxy)-exo-4-(hydroxymethyl)-cis-bicyclo<3.3.0>oct-2-ene 5.The key feature of the synthesis is a 'one-pot' hydrogenolysis-cyclopentadienol clea

Full text of DOI:10.1039/P19940000061

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