Journal of Organic Chemistry p. 474 - 481 (1990)
Update date:2022-08-02
Topics:
Feldman, Ken S.
Bobo, John S.
Ensel, Susan M.
Lee, Yoon B.
Weinreb, Paul H.
The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trans-anti-trans-norbornadien trimer 5.Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers.Lactonization studies with template diol 10 provide a useful measure of the "effective molecular size" of the template.
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