Tris (trimethylsilyl)silane in the deoxygenation of long chain unsaturated alcohols converts cis to trans isomers

DOI: 10.1016/0040-4039(92)88137-T

Source and publish data:

Tetrahedron Letters p. 2045 - 2048 (1992)

Update date:2022-08-02

Topics:

Authors:

Johnson Johnson

Poulos Poulos

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Article abstract of DOI:10.1016/0040-4039(92)88137-T

During radical deoxygenation reactions tris (trimethylsilyl)silane can cause cis to trans isomerization and reduction of remote double bonds in contrast to tributyltin hydride.

Full text of DOI:10.1016/0040-4039(92)88137-T

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