Tris (trimethylsilyl)silane in the deoxygenation of long chain unsaturated alcohols converts cis to trans isomers

DOI: 10.1016/0040-4039(92)88137-T

Source and publish data:

Tetrahedron Letters p. 2045 - 2048 (1992)

Update date:2022-08-02

Topics:

Authors:

Johnson Johnson

Poulos Poulos

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)88137-T

During radical deoxygenation reactions tris (trimethylsilyl)silane can cause cis to trans isomerization and reduction of remote double bonds in contrast to tributyltin hydride.

Full text of DOI:10.1016/0040-4039(92)88137-T

Products guided by the article

Product name:C₃₉H₆₅NO₄S

Cas No:141735-39-9

R&D Labs maybe for 141735-39-9

Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road
Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
NEM CHEMICAL CO.，LTD

website:http://www.NEM.COM.CN

Contact:+86-393-4411771

Address:The west section of shengli Road,Puyang,Henan Province,China
LinHai Cina Chemical Co., LTD.

Contact:0576-85580989

Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing

Relevant to this article

Optimization of Cyclic Plasmin Inhibitors: From Benzamidines to Benzylamines

Doi:10.1021/acs.jmedchem.6b00606
(2016)
FUNCTIONALIZED 2-AZABICYCLO(3.3.1)NONANES. VII. A NEW SYNTHESIS OF 4-AZATRICYCLO(5.2.2.0^4,8)UNDECAN-11-ONE

Doi:10.1016/S0040-4020(01)89966-X
(1987)
Thorium(IV) and uranium(IV) halide complexes supported by bulky β-diketiminate ligands

Doi:10.1021/om3010965
(2013)
Study of the O-glycidylation of natural phenolic compounds. the relationship between the phenolic structure and the reaction mechanism

Doi:10.1016/j.tet.2012.11.079
(2013)
Design and synthesis of a C₄-symmetrical hard-soft ditopic metal receptor by calixarene-porphyrin coupling

Doi:10.1039/P19950001883
(1995)
Synthesis of spiroindoline phytoalexin (S)-(-)-spirobrassinin and its unnatural (R)-(+)-enantiomer

Doi:10.1016/j.tet.2012.11.067
(2013)

Article Doi