Tris (trimethylsilyl)silane in the deoxygenation of long chain unsaturated alcohols converts cis to trans isomers

DOI: 10.1016/0040-4039(92)88137-T

Source and publish data:

Tetrahedron Letters p. 2045 - 2048 (1992)

Update date:2022-08-02

Topics:

Authors:

Johnson Johnson

Poulos Poulos

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)88137-T

During radical deoxygenation reactions tris (trimethylsilyl)silane can cause cis to trans isomerization and reduction of remote double bonds in contrast to tributyltin hydride.

Full text of DOI:10.1016/0040-4039(92)88137-T

Products guided by the article

Product name:C₃₉H₆₅NO₄S

Cas No:141735-39-9

R&D Labs maybe for 141735-39-9

Jiacheng-Chem Enterprises Limited(expird)

Contact:86-571-86711508

Address:19 Floor, CIBC Holley International Building, No. 198,Wuxing Road, Hangzhou, China,310020
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Shanghai Hongbang Medical Technology CO.,. Ltd

Contact:13671516988 /18917636693

Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.

Relevant to this article

Optimization of Cyclic Plasmin Inhibitors: From Benzamidines to Benzylamines

Doi:10.1021/acs.jmedchem.6b00606
(2016)
FUNCTIONALIZED 2-AZABICYCLO(3.3.1)NONANES. VII. A NEW SYNTHESIS OF 4-AZATRICYCLO(5.2.2.0^4,8)UNDECAN-11-ONE

Doi:10.1016/S0040-4020(01)89966-X
(1987)
Thorium(IV) and uranium(IV) halide complexes supported by bulky β-diketiminate ligands

Doi:10.1021/om3010965
(2013)
Study of the O-glycidylation of natural phenolic compounds. the relationship between the phenolic structure and the reaction mechanism

Doi:10.1016/j.tet.2012.11.079
(2013)
Design and synthesis of a C₄-symmetrical hard-soft ditopic metal receptor by calixarene-porphyrin coupling

Doi:10.1039/P19950001883
(1995)
Synthesis of spiroindoline phytoalexin (S)-(-)-spirobrassinin and its unnatural (R)-(+)-enantiomer

Doi:10.1016/j.tet.2012.11.067
(2013)

Article Doi