HOMOLYTIC DISPLACEMENT AT CARBON: FIRST EXAMPLE OF α-ATTACK IN THE ALLENYL AND PROPARGYL COBALOXIMES

DOI: 10.1016/S0040-4039(00)85094-7

Source and publish data:

Tetrahedron Letters p. 4905 - 4908 (1986)

Update date:2022-08-03

Topics:

Authors:

Gupta, B.D.

Roy, Sujit

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Article abstract of DOI:10.1016/S0040-4039(00)85094-7

The reactions of allenyl and propalgyl cobaloximes with organosulphonyl chlorides under anaerobic and photochemical conditions form sulphones by a novel homolytic attack at the α carbon to the metal.

Full text of DOI:10.1016/S0040-4039(00)85094-7

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