Tetrahedron Letters p. 949 - 950 (1987)
Update date:2022-08-03
Topics:
Jefford, Charles W.
Sledeski, Adam W.
Boukouvalas, John
The reaction of 2-trimethylsiloxyfuran, 3,3-dimethylallyl bromide and silver trifluoroacetate produced (3,3-dimethylallyl)-4-but-2-en-4-olide with high double regiodifferentiation.The latter compound on treatment with lithium dimethylcuprate gave (+/-)-eldanolide in high yield.
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