Synthesis p. 415 - 418 (1987)
Update date:2022-08-05
Topics: Reagent Carbon Dioxide Electrophilic Attack Benzylamine Nucleophilic Centers α-Substitution Benzyl Alcohol
Katritzky, Alan R.
Fan, Wei-Qiang
Akutagawa, Kunihiko
Benzyl alcohol is converted into a variety of α-substituted derivatives by a one-pot sequence involving lithiation of an intermediate hemicarbonate ester.Benzylamine is similarly converted by a one-pot sequence to α-substituted benzylamines: here an intermediate carbamate salt is involved.
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