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120068-37-3

Basic Information
CAS No.: 120068-37-3
Name: Fipronil
Molecular Structure:
Molecular Structure of 120068-37-3 (Fipronil)
Formula: C12H4Cl2F6N4OS
Molecular Weight: 437.15
Synonyms: 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-(trifluoromethylsulfinyl)pyrazole-3-carbonitrile;MB 46030;RM 1601;Fipronil (JAN);1H-Pyrazole-3-carbonitrile, 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-((trifluoromethyl)sulfinyl)-;Fluocyanobenpyrazole;Fipronil 95%TC;
EINECS: 424-610-5
Density: 1.87 g/cm3
Melting Point: 200-201 ºC
Boiling Point: 510.1 ºC at 760 mmHg
Flash Point: 262.3 ºC
Solubility: 1.9-2.4 mg 1l-1 (20 °C)
Appearance: clear colorless or slightly yellow liquid
Hazard Symbols: ToxicT,DangerousN
Risk Codes: 23/24/25-48/25-50/53-55-57
Safety: S26-36/37/39-45-60-61
Transport Information:
PSA: 103.91000
LogP: 5.72608
Synthetic route
20621-29-8

trifluoromethylsulfinyl chloride

120068-79-3

5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole

120068-37-3

fipronil

Conditions
ConditionsYield
With dimethylamine p-toluenesulfonate for 10h; Heating;99%
With dimethylamine p-toluenesulfonate at 50℃; for 8h;92%
With benzyltrimethylammonium chloride In 1,2-dichloro-ethane at 35℃; for 2h; Temperature; Industrial scale;90.3%
120067-83-6

5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile

120068-37-3

fipronil

Conditions
ConditionsYield
Stage #1: 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile With dichloro-acetic acid; sulfuric acid at 15℃; for 0.5h;
Stage #2: With dihydrogen peroxide In water at 15℃; Product distribution / selectivity;
98%
With caro's acid In dichloromethane at 0 - 5℃; Reagent/catalyst; Industrial scale;97.9%
With dihydrogen peroxide In dichloro-acetic acid; water; trichloroacetic acid at 20℃; for 2h; Product distribution / selectivity;95%
120067-83-6

5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile

A

120068-37-3

fipronil

B

120068-36-2

fipronil sulfone

Conditions
ConditionsYield
With dihydrogen peroxide; trifluoroacetic acid In dichloromethane at 10 - 12℃; for 3h;A 96%
B n/a
Stage #1: 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile With trifluoroacetic acid for 0.25h;
Stage #2: With Oxone at -15℃; Product distribution / selectivity;
A 55.4%
B n/a
Stage #1: 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile With trifluoroacetic acid for 0.25h; Industry scale;
Stage #2: With Oxone at -15℃; Product distribution / selectivity; Industry scale;
20621-29-8

trifluoromethylsulfinyl chloride

2840-22-4

dimethylamine p-toluenesulfonate

120068-79-3

5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole

120068-37-3

fipronil

Conditions
ConditionsYield
In water; toluene88%
2926-29-6

Langlois reagent

120068-79-3

5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole

120068-37-3

fipronil

Conditions
ConditionsYield
With trichlorophosphate; dimethylamine p-toluenesulfonate at 40℃; for 14h; Product distribution / selectivity;80.2%
With thionyl chloride; dimethylamine p-toluenesulfonate at 40℃; for 10h; Product distribution / selectivity;74.8%
Stage #1: Langlois reagent With thionyl chloride; dimethylamine p-toluenesulfonate In toluene at 0 - 5℃; for 0.5h;
Stage #2: 5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole In toluene at 5 - 50℃; for 6.08333h; Product distribution / selectivity;
73%
41804-89-1

potassium triflinate

120068-79-3

5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole

120068-37-3

fipronil

Conditions
ConditionsYield
Stage #1: potassium triflinate With thionyl chloride; triethylamine hydrochloride In toluene at 0 - 5℃; for 0.5 - 0.833333h;
Stage #2: 5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole In toluene at 5 - 35℃; for 11.75h; Product distribution / selectivity;
66%
Stage #1: potassium triflinate With thionyl chloride; pyridine hydrochloride In toluene at 0 - 5℃; for 0.833333h;
Stage #2: 5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole In toluene at 5 - 35℃; for 11.75h; Product distribution / selectivity;
Stage #1: potassium triflinate With thionyl chloride; trimethylamine hydrochloride In toluene at 0 - 5℃; for 0.833333h;
Stage #2: 5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole In toluene at 5 - 35℃; for 11.75h; Product distribution / selectivity;
208652-17-9

5-amino-4-trifluoromethylsulfinyl-1-(2,6-dichloro-4-trifluoromethylphenyl)-3-thiocarbamoylpyrazole

120068-37-3

fipronil

Conditions
ConditionsYield
With hydrogenchloride In water; acetonitrile Product distribution / selectivity;
In water; acetonitrile Product distribution / selectivity; fluorescent light;
In water; acetonitrile at 65℃; Product distribution / selectivity;
7446-09-5

sulfur dioxide

120067-83-6

5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile

120068-37-3

fipronil

Conditions
ConditionsYield
With dihydrogen peroxide; boric acid; trifluoroacetic acid In chlorobenzene
120067-94-9

5-amino-3-bromo-1-(2,6-dichloro-4-trifluoromethylphenyl)-4-trifluoromethylthiopyrazole

A

120068-43-1

5-amino-3-bromo-1-(2,6-dichloro-4-trifluoromethylphenyl)-4-trifluoromethylsulphinylpyrazole

B

120068-37-3

fipronil

34642-42-7

trifluoromethanesulfinic acid

120068-79-3

5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole

120068-37-3

fipronil

Conditions
ConditionsYield
Stage #1: trifluoromethanesulfinic acid With thionyl chloride; triethylamine In toluene at 0 - 5℃; for 0.5h;
Stage #2: 5-amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole; triethylamine hydrochloride In toluene at 50℃; for 6h; Product distribution / selectivity;
With thionyl chloride; N,N-dimethylisopropyl amine; potassium chloride; isopropyl-dimethyl-amine; hydrochloride In ethylbenzene at 0 - 35℃; for 11.75h; Inert atmosphere;
24279-39-8

2,6-dichloro-4-(trifluoromethyl)aniline

120068-37-3

fipronil

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: nitrosylsulfuric acid; acetic acid / 30 - 55 °C
1.2: 0 - 15 °C
2.1: dichloromethane
3.1: boric acid; trichloroacetic acid; dihydrogen peroxide / chlorobenzene; water / 20 h / 15 - 20 °C
View Scheme
328-84-7

1,2-dichloro-4-(trifluoromethyl)benzene

120068-37-3

fipronil

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: dimethylsulfone; potassium fluoride; ammonia / 6 h / 30 - 235 °C / 18751.9 - 19502 Torr / Autoclave
2.1: sulfuryl dichloride; 1-methyl-pyrrolidin-2-one / 1-methyl-pyrrolidin-2-one; chlorobenzene / 8 h / 55 - 60 °C
3.1: nitrosylsulfuric acid; acetic acid / 30 - 55 °C
3.2: 0 - 15 °C
4.1: dichloromethane
5.1: boric acid; trichloroacetic acid; dihydrogen peroxide / chlorobenzene; water / 20 h / 15 - 20 °C
View Scheme
Multi-step reaction with 5 steps
1.1: 1-methyl-pyrrolidin-2-one; potassium fluoride; ammonia / 10 h / 245 - 250 °C / 22502.3 - 30003 Torr / Autoclave
2.1: sulfuryl dichloride; 1-methyl-pyrrolidin-2-one / 1-methyl-pyrrolidin-2-one; chlorobenzene / 8 h / 55 - 60 °C
3.1: nitrosylsulfuric acid; acetic acid / 30 - 55 °C
3.2: 0 - 15 °C
4.1: dichloromethane
5.1: boric acid; trichloroacetic acid; dihydrogen peroxide / chlorobenzene; water / 20 h / 15 - 20 °C
View Scheme
39885-50-2

2-chloro-4-(trifluoromethyl)aniline

120068-37-3

fipronil

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: sulfuryl dichloride; 1-methyl-pyrrolidin-2-one / 1-methyl-pyrrolidin-2-one; chlorobenzene / 8 h / 55 - 60 °C
2.1: nitrosylsulfuric acid; acetic acid / 30 - 55 °C
2.2: 0 - 15 °C
3.1: dichloromethane
4.1: boric acid; trichloroacetic acid; dihydrogen peroxide / chlorobenzene; water / 20 h / 15 - 20 °C
View Scheme
7722-84-1

dihydrogen peroxide

120067-83-6

5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile

120068-37-3

fipronil

Conditions
ConditionsYield
With hydrogenchloride; sodium tungstate In water; 1,2-dichloro-ethane at 2 - 8℃; Large scale;
122-51-0

orthoformic acid triethyl ester

120068-37-3

fipronil

3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)-5-ethoxymethylideneamino-4-trifluoromethylsulfinylpyrazole

Conditions
ConditionsYield
99%
99%
555-16-8

4-nitrobenzaldehdye

120068-37-3

fipronil

1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((4-nitro-benzylidene)amino)-4-(trifluoromethanesulfinyl)-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 200℃; for 3h; Temperature; Time; Molecular sieve; High pressure; Sonication; Autoclave; Sealed tube;98.9%
109-69-3

n-Butyl chloride

120068-37-3

fipronil

N-5-butylamino-1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoromethylsulfinyl-1H-pyrazole

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 80℃; for 8h; Sonication;96.7%
459-57-4

4-fluorobenzaldehyde

120068-37-3

fipronil

1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-(4-fluorobenzylideneamino)-4-(trifluoromethylsulfinyl)-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 200℃; for 3h; Temperature; Time; Molecular sieve; High pressure; Sonication; Autoclave; Sealed tube;96.5%
With toluene-4-sulfonic acid In chlorobenzene for 1h; Molecular sieve; Microwave irradiation; Sealed tube;73%
1694-92-4

2-Nitrobenzenesulfonyl chloride

120068-37-3

fipronil

1225373-70-5

C18H7Cl2F6N5O5S2

Conditions
ConditionsYield
With sodium hydride In ethyl acetate at 0 - 20℃;96%
With sodium hydride In ethyl acetate at 2 - 20℃; for 4h;79.3%
110-52-1

1,4-dibromo-butane

120068-37-3

fipronil

N-bis(1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoromethylsulfinyl-1H-pyrazol-5ylamino)butyl

Conditions
ConditionsYield
With potassium hydroxide In N,N-dimethyl-formamide at 20℃; for 3h; Sonication; Microwave irradiation; Heating;95.2%
1014394-95-6

1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-(4-bromophenylsulfonylamino)-1H-pyrazole-3-carbonitrile

120068-37-3

fipronil

1225373-68-1

C18H7BrCl2F6N4O3S2

Conditions
ConditionsYield
With sodium hydride In ethyl acetate at 0 - 20℃;95%
100-52-7

benzaldehyde

120068-37-3

fipronil

5-(benzylideneamino)-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylsulfinyl)-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 200℃; for 3h; Temperature; Time; Molecular sieve; High pressure; Sonication; Autoclave; Sealed tube;94.8%
With toluene-4-sulfonic acid In toluene for 1h; Reagent/catalyst; Molecular sieve; Microwave irradiation; Sealed tube;84%
55854-46-1

5-bromo-2-thiophenesulfonyl chloride

120068-37-3

fipronil

C16H5BrCl2F6N4O3S3

Conditions
ConditionsYield
With sodium hydride In ethyl acetate at 0 - 20℃;93%
109-65-9

1-bromo-butane

120068-37-3

fipronil

N-5-butylamino-1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoromethylsulfinyl-1H-pyrazole

Conditions
ConditionsYield
With potassium hydroxide In N,N-dimethyl-formamide at 20℃; for 3h; Time; Sonication; Microwave irradiation; Heating;92.6%
With potassium hydroxide In N,N-dimethyl-formamide at 20℃; for 1h;92.6%
104-87-0

4-methyl-benzaldehyde

120068-37-3

fipronil

1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((4-methylbenzylidene)amino)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 200℃; for 3h; Temperature; Time; Molecular sieve; High pressure; Sonication; Autoclave; Sealed tube;92.6%
591-31-1

3-methoxy-benzaldehyde

120068-37-3

fipronil

1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((3-methoxybenzylidene)amino)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 200℃; for 3h; Temperature; Time; Molecular sieve; High pressure; Sonication; Autoclave; Sealed tube;91.8%
105-36-2

ethyl bromoacetate

120068-37-3

fipronil

1430089-22-7

ethyl N-[3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)-phenyl]-4-[(trifluoromethyl)-sulfinyl]-1H-pyrazol-5-yl]-aminoacetate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 20℃; for 3h; Cooling with ice;91%
4070-75-1

1,4-diphenyl-but-2-ene-1,4-dione

120068-37-3

fipronil

C28H15ClF6N4O3S

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 50℃;91%
14077-58-8

ethoxyacetyl chloride

121-44-8

triethylamine

120068-37-3

fipronil

379215-14-2

triethylamine salt of 1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoromethylsulfinyl-5-(ethoxyacetamido)pyrazole

Conditions
ConditionsYield
In tetrahydrofuran at 60℃; for 1.5h;90%
98-09-9

benzenesulfonyl chloride

120068-37-3

fipronil

1225373-74-9

C18H8Cl2F6N4O3S2

Conditions
ConditionsYield
With sodium hydride In ethyl acetate at 0 - 20℃;90%
120068-37-3

fipronil

23055-10-9

1,4-dimethyl but-2-enedioate

C18H11ClF6N4O5S

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 50℃;90%
35076-92-7

1,4-bibromocyclohexane

120068-37-3

fipronil

N-bis(1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoromethylsulfinyl-1H-pyrazol-5-ylamino)cyclohexyl

Conditions
ConditionsYield
With potassium hydroxide In N,N-dimethyl-formamide at 20℃; for 3h; Sonication; Microwave irradiation; Heating;89.5%
623-24-5

1,4-bis(bromomethyl)benzene

120068-37-3

fipronil

N-bis(1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoromethylsulfinyl-1H-pyrazol-5ylamino)benzyl

Conditions
ConditionsYield
With potassium hydroxide In toluene at 20℃; for 3h; Sonication; Microwave irradiation; Heating;89.3%
135-02-4

ortho-anisaldehyde

120068-37-3

fipronil

1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((2-methoxybenzylidene)amino)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 200℃; for 3h; Temperature; Time; Molecular sieve; High pressure; Sonication; Autoclave; Sealed tube;88.7%
98-59-9

p-toluenesulfonyl chloride

120068-37-3

fipronil

1225373-72-7

C19H10Cl2F6N4O3S2

Conditions
ConditionsYield
With sodium hydride In ethyl acetate at 0 - 20℃;88%

C7H12O7S

120068-37-3

fipronil

C18H11ClF6N4O5S

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 50℃;88%
123-11-5

4-methoxy-benzaldehyde

120068-37-3

fipronil

1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((4-methoxybenzylidene)amino)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 200℃; for 3h; Temperature; Time; Molecular sieve; High pressure; Sonication; Autoclave; Sealed tube;87.4%
With toluene-4-sulfonic acid In 1,3,5-trimethyl-benzene for 1h; Molecular sieve; Microwave irradiation; Sealed tube;78%
17299-97-7

α,α',α''-trichloromesitylene

120068-37-3

fipronil

N-1,3,5-tri(1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoromethylsulfinyl-1H-pyrazol-5ylamino)benzyl

Conditions
ConditionsYield
With potassium hydroxide In N,N-dimethyl-formamide at 20℃; for 3h; Sonication; Microwave irradiation; Heating;87.2%
14077-58-8

ethoxyacetyl chloride

120068-37-3

fipronil

potassium salt of 1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoromethylsulfinyl-5-(ethoxyacetamido)pyrazole

Conditions
ConditionsYield
With potassium hydroxide In acetonitrile at -5℃; for 4h;87%
Stage #1: ethoxyacetyl chloride; fipronil With triethylamine In tetrahydrofuran at 30℃; for 5h;
Stage #2: With hydrogenchloride In tetrahydrofuran; dichloromethane; water pH=2;
Stage #3: With potassium carbonate In tetrahydrofuran; dichloromethane; water
65%
553-90-2

Dimethyl oxalate

120068-37-3

fipronil

N,N'-bis[3-cyano-4-trifluoromethylsulfinyl-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazolyl]ethanediamide

Conditions
ConditionsYield
With sodium ethanolate In toluene at 120℃; for 12h; Temperature; Time;86.5%
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    120068-37-3

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    Fipronil 99%min CAS No.:120068-37-3 Name Fipronil Synonyms 5-Amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Molecular Structure Molecular Formula C12H4Cl2F6N4OS

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    120068-37-3

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    Product Name: Fipronil CAS: 120068-37-3 MF: C12H4Cl2F6N4OS MW: 437.15 EINECS: 424-610-5 Mol File: 120068-37-3.mol Fipronil Structure Fipronil Chemical Properties Melting point 200-201°C Boiling point 510.1±50.0

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    120068-37-3

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    1.Product name: Fipronil 2.CAS No.120068-37-3 3.MF:C12H4Cl2F6N4OS 4.Assay: 95% min. or 98.0% min. or 99.0% min 5.Appearance:White crysta Appearance:white crystal Storage:Store in dry and cool place with good seal Package:1KG/ foil bag, 25kg/fib

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Specification

The Fipronil, with the CAS registry number 120068-37-3,is also known as 5-Amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H- pyrazole-3-carbonitrile. It belongs to the product categories of pharmaceuticals;ectoparasiticide;api;insecticide. This chemical's molecular formula is C12H4Cl2F6N4OS and molecular weight is 437.15.What's more,Its systematic name is 1H-Pyrazole-3-carbonitrile, 5-amino-1-(2,6-dichloro-4-(trifluoromethyl) phenyl)-4-((trifluoromethyl)sulfinyl)-. It is a White SOlid which is a broad spectrum insecticide which actively disrupts the CNS of contacted insects by blocking the passage of chloride ions through GABA receptors.

Physical properties about Fipronil are:
(1)ACD/LogP:  3.975; (2)# of Rule of 5 Violations:  0; (3)ACD/LogD (pH 5.5):  3.98; (4)ACD/LogD (pH 7.4):  3.98; (5)ACD/BCF (pH 5.5):  618.18; (6)ACD/BCF (pH 7.4):  618.18; (7)ACD/KOC (pH 5.5):  3463.23; (8)ACD/KOC (pH 7.4):  3463.23; (9)#H bond acceptors:  5; (10)#H bond donors:  2; (11)#Freely Rotating Bonds:  3; (12)Index of Refraction:  1.618; (13)Molar Refractivity:  81.858 cm3; (14)Molar Volume:  233.684 cm3; (15)Surface Tension:  52.9809989929199 dyne/cm; (16)Density:  1.871 g/cm3; (17)Flash Point:  262.271 °C; (18)Enthalpy of Vaporization:  78.073 kJ/mol; (19)Boiling Point:  510.054 °C at 760 mmHg; (20)Vapour Pressure:  0 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES:FC(F)(F)S(=O)c2c(C#N)nn(c1c(Cl)cc(cc1Cl)C(F)(F)F)c2N;
(2)Std. InChI:InChI=1S/C12H4Cl2F6N4OS/c13-5-1-4(11(15,16)17)2-6(14)8(5)24-10(22)9(7(3-21)23-24)26(25)12(18,19)20/h1-2H,22H2;
(3)Std. InChIKey:ZOCSXAVNDGMNBV-UHFFFAOYSA-N.

Safety Information of Fipronil:
The Fipronil is toxic by inhalation, in contact with skin and if swallowed and toxic to fauna and bees. And it is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,it should be avoided release to the environment. Refer to special instructions / safety data sheets. When you use it, wear suitable protective clothing, gloves and eye/face protection.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) .This material and its container must be disposed of as hazardous waste.

Uses of  Fipronil:
Fipronil is used as the active ingredient in Frontline Top Spot at about 9.8% concentration, and is used together with (S)-methoprene (8.8%) in Frontline Plus, a topical flea and tick control commonly used on dogs and cats. Fipronil(120068-37-3) kills adult fleas before they lay eggs.Fipronil(120068-37-3) is also the active ingredient in GardenTech's Over N Out season long fire ant control product.

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