Synthesis of Enantiopure 2-Malonylvinyl Sulfoxides via Addition-Elimination Reactions of 2-Halo- and 2-(Mesyloxy)vinyl Sulfoxides

DOI: 10.1021/jo00090a042

Source and publish data:

Journal of Organic Chemistry p. 3193 - 3201 (1994)

Update date:2022-07-30

Topics:

Authors:

Marino, Joseph P.

Laborde, Edgardo

Deering, Carl F.

Paley, Robert S.

Ventura, Maria Paz

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Article abstract of DOI:10.1021/jo00090a042

Enantiomerically pure (E)-2-bromo- and (E)-2-iodovinyl sulfoxides 3a and 3b have been prepared in multigram quantities from (E)-1,2-bis(tri-n-butylstannyl)ethene; enantiomerically pure (E)-2-(mesyloxy)vinyl sulfoxide 3c has been synthesized by reaction of

Full text of DOI:10.1021/jo00090a042

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