Bulletin of the Chemical Society of Japan p. 1954 - 1956 (1987)
Update date:2022-08-05
Topics:
Inoue, Yoshiharu
Hydroboration of 5-vinyl-2-norbornene (1) with 9-BBN mainly affords 5-(2-hydroxyethyl)-2- norbornene (2).The iodo ether cyclization of 2 can convert only endo-5-(2-hydroxyethyl)-2-norbornene (2b) to iodo ether 10, followed by reductive elimination and subsequent dehydration to furnish endo-5-vinyl-2-norbornene (1b) which has not been isolated in pure form.Meanwhile, unreacted exo-5-(2-hydroxyethyl)-2-norbornene (2a) produces exo-5-vinyl-2-norbornene (1a) via dehydration.
View MoreContact:86-21-34622192，13917187091，21-34622765
Address:No. 500 Caobao Road Shanghai P.R China
JiYi Chemical (Beijing) Co., Ltd.
Contact:+86-10-89385733
Address:Shilou Town of Fangshan District， Beijing
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.
Contact:+86-21-39971718
Address:859 jiadingchengliu shanghai
Nanjing Fayekong Chemcial Co.,Ltd(expird)
Contact:86-25-58813444
Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
website:http://www.antaibio.com
Contact:86-21-60939051,60939771
Address:1518#,ZHANGYANG ROAD
Doi:10.1246/cl.1987.1095
(1987)Doi:10.1080/10426500701641262
(2008)Doi:10.1016/j.inoche.2007.10.001
(2008)Doi:10.1002/jlcr.878
(2004)Doi:10.1016/j.bmcl.2013.11.057
(2014)Doi:10.1016/S0968-0896(98)00050-9
(1998)
