On Baldwin's Kinetic Barrier Against 5-(Enol-endo)-exo-trigonal Closures: a Comparison of Ionic and Analogous Radical Reactions, and a New Synthesis of Cyclopentanones

DOI: 10.1039/c39870001520

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Journal of the Chemical Society. Chemical communications p. 1520 - 1523 (1987)

Update date:2022-08-03

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Authors:

Clive, Derrick L. J.

Cheshire, David R.

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Article abstract of DOI:10.1039/c39870001520

The kinetic barrier that impedes ionic 5-(enol-endo)-exo-trigonal closures does not play such a dominant role in the case of α-oxo radicals (17); these radicals cyclize directly to cyclopentanones in a process that constitutes a synthetic method for conve

Full text of DOI:10.1039/c39870001520

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